Synthesis of [2,3,4,5,6-2H5]phenyl glucosinolate

被引：6
|
作者：
Bialecki, Jason B. [1 ]
Ruzicka, Josef [1 ]
Attygalle, Athula B. [1 ]
机构：
[1] Stevens Inst Technol, Ctr Mass Spectrometry, Dept Chem & Chem Biol, Hoboken, NJ 07030 USA
来源：
JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS | 2007年 / 50卷 / 7-8期
关键词：
glucosinolates; phenyl glucosinolate; collision-induced dissociation (CID); internal standard; electrospray-ionization mass spectrometry;
D O I：
10.1002/jlcr.1407
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Starting from commercially available [2,3,4,5,6-H-2(5)]benzoic acid, [2,3,4,5,6-H-2(5)]phenyl glucosinolate was synthesized. Under negative-ion electrospray-ionization mass spectrometric conditions, this compound affords a peak at m/z 399. Since this m/z value is not known from the ions derived from natural glucosinolates, the [2,3,4,5,6-H-2(6)]phenyl glucosinolate reported here is useful as an internal standard for the quantification of glucosinolates by negative-ion mass spectrometry (MS) and liquid chromatography (LC)/MS techniques. Copyright (c) 2007 John Wiley & Sons, Ltd.
引用
收藏
页码：711 / 715
页数：5
相关论文
共 50 条
  • [1] Incorporation of [2,3,4,5,6-2H5] phenylalanine, [3,5-2H2]tyrosine, and [2,4,5,6,7-2H5]tryptophan into the Bacteriorhodopsin Molecule of Halobacterium halobium
    Mosin, OV
    Skladnev, DA
    Shvets, VI
    APPLIED BIOCHEMISTRY AND MICROBIOLOGY, 1999, 35 (01) : 29 - 37
  • [2] 2,3,4,5,6-Pentabromophenyl phenyl ether
    Eriksson, L
    Hu, JW
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : O794 - O796
  • [3] Diastereoselective Synthesis of 2,3,4,5,6-Pentafluoroheptanes
    Farran, Daniel
    Slawin, Alexandra M. Z.
    Kirsch, Peer
    O'Hagan, David
    JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (18): : 7168 - 7171
  • [4] 2,3,4,5,6-pentafluorobenzamide
    Gdaniec, M
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1642 - O1644
  • [5] Synthesis of (R)-(2,3,4,5,6-pentadeuterophenyl)oxirane
    Matthews, L
    Ellis, MK
    Cullis, PN
    Farmer, PB
    JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 1997, 39 (06): : 479 - 486
  • [6] 2,3,4,5,6-pentabromophenol
    Betz, Richard
    Kluefers, Peter
    Mayer, Peter
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1921 - U3736
  • [7] 2,3,4,5,6-Pentafluoroaniline
    Gdaniec, Maria
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2954 - U2854
  • [8] FORMATION OF 2,3,4,5,6-PENTAFLUOROPHENYLCARBONIMIDOYL DICHLORIDE BY COPYROLYSIS OF 2,3,4,5,6-PENTAFLUOROANILINE WITH CHLOROFORM
    SAVCHENKO, TI
    PETROVA, TD
    PLATONOV, VE
    YAKOBSON, GG
    JOURNAL OF FLUORINE CHEMISTRY, 1977, 9 (06) : 505 - 508
  • [9] 2,3,4,5,6-Pentabromobenzoic Acid
    Taydakov, Ilya V. V.
    Vlasova, Tatiana S. S.
    Belousov, Yury A. A.
    Zanizdra, Sergey R. R.
    Gontcharenko, Victoria E. E.
    MOLBANK, 2022, 2022 (04)
  • [10] 1,10-Phenanthrolinium 2,3,4,5,6-pentafluorobenzoate-2,3,4,5,6-pentafluorobenzoic acid (1/2)
    Zhang, Xiangdong
    Men, Yanmei
    Yan, Xianghua
    Ge, Chunhua
    Kong, Yuxia
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2535 - +
12345