Hydrothermal synthesis of metastable γ-manganese sulfide crystallites

被引：35

作者：

Zhang, Y

Wang, H ^{[1
]}

Wang, B

Xu, HY

Yan, H

Yoshimura, M

机构：

[1] Beijing Polytech Univ, China Educ Ministry, Key Lab Adv Funct Mat, Beijing 100022, Peoples R China

[2] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

OPTICAL MATERIALS | 2003年 / 23卷 / 1-2期

关键词：

manganese sulfide; metastable phase; hydrothermal technique;

D O I：

10.1016/S0925-3467(02)00334-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A hydrothermal route has been adopted to prepare metastable wurtzite-type (gamma) manganese sulfide (MnS) crystallites via the reaction of manganese acetate (Mn(CH3COO)(2)) and thioacetamide in water at 60-130 degreesC. Experiments show that the control of reaction temperature and time is important to the target phase. It is suggested that kinetics plays a predominant role in the formation of gamma-MnS under the hydrothermal conditions. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：433 / 437

页数：5

相关论文

共 18 条

[1]

Akhter M. A., 1988, THIN SOLID FILMS, V158, P83

[2] Solvothermal processes: a route to the stabilization of new materials [J].

Demazeau, G .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (01) :15-18

[3] AXIAL RATIOS OF MX COMPOUNDS WITH WURTZITE STRUCTURE [J].

FLEET, ME .

MATERIALS RESEARCH BULLETIN, 1976, 11 (09) :1179-1183

[4] OPTICAL-PROPERTIES OF (ZN, MN) AND (CD, MN) CHALCOGENIDE MIXED-CRYSTALS AND SUPERLATTICES [J].

GOEDE, O ;

HEIMBRODT, W .

PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 1988, 146 (01) :11-62

[5] OPTICAL STUDY OF PHASE-TRANSITION FROM TETRAHEDRALLY INTO OCTAHEDRALLY COORDINATED MNS [J].

GOEDE, O ;

HEIMBRODT, W ;

WEINHOLD, V ;

SCHNURER, E ;

EBERLE, HG .

PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1987, 143 (02) :511-518

[6] Synthesis of cubic boron nitride at low-temperature and low-pressure conditions [J].

Hao, XP ;

Cui, DL ;

Shi, GX ;

Yin, YQ ;

Xu, XG ;

Wang, JY ;

Jiang, MH ;

Xu, XW ;

Li, YP ;

Sun, BQ .

CHEMISTRY OF MATERIALS, 2001, 13 (08) :2457-2459

[7] MECHANISMS OF THERMAL TRANSFORMATION OF ZINC BLENDE TO [NACL] IN MNS CRYSTALS [J].

KENNEDY, SW ;

HARRIS, K ;

SUMMERVILLE, E .

JOURNAL OF SOLID STATE CHEMISTRY, 1980, 31 (03) :355-359

[8] Process and characterisation of chemical bath deposited manganese sulphide (MnS) thin films [J].

Lokhande, CD ;

Ennaoui, A ;

Patil, PS ;

Giersig, M ;

Muller, M ;

Diesner, K ;

Tributsch, H .

THIN SOLID FILMS, 1998, 330 (02) :70-75

[9] Metastable MnS crystallites through solvothermal synthesis [J].

Lu, J ;

Qi, PF ;

Peng, YY ;

Meng, ZY ;

Yang, ZP ;

Yu, WC ;

Qian, YT .

CHEMISTRY OF MATERIALS, 2001, 13 (06) :2169-2172

[10] Evidence for aqueous clusters as intermediates during zinc sulfide formation [J].

Luther, GW ;

Theberge, SM ;

Rickard, DT .

GEOCHIMICA ET COSMOCHIMICA ACTA, 1999, 63 (19-20) :3159-3169