Carbonate-Catalyzed Room-Temperature Selective Reduction of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Bis(hydroxymethyl)furan

被引：21

作者：

Long, Jingxuan ^{[1
]}

Zhao, Wenfeng ^{[1
]}

Xu, Yufei ^{[1
]}

Li, Hu ^{[1
]}

Yang, Song ^{[1
]}

机构：

[1] Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Key Lab Green Pesticide & Agr Bioengn,Ctr R&D Fin, Minist Educ,State Local Joint Lab Comprehens Util, Guiyang 550025, Guizhou, Peoples R China

来源：

CATALYSTS | 2018年 / 8卷 / 12期

基金：

中国国家自然科学基金;

关键词：

biomass conversion; biofuels; hydrogenation; green chemistry; sustainable catalysis; TRANSFER HYDROGENATION; FURFURYL ALCOHOL; CONVERSION; ACID; HYDROSILYLATION; CHEMISTRY; FRUCTOSE; SOLVENTS; AMIDES; SUGARS;

D O I：

10.3390/catal8120633

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic reduction of 5-hydroxymethylfurfural (HMF), deemed as one of the key bio-based platform compounds, is a very promising pathway for the upgrading of biomass to biofuels and value-added chemicals. Conventional hydrogenation of HMF is mainly conducted over precious metal catalysts with high-pressure hydrogen. Here, a highly active, sustainable, and facile catalytic system composed of K2CO3, Ph2SiH2, and bio-based solvent 2-methyltetrahydrofuran (MTHF) was developed to be efficient for the reduction of HMF. At a low temperature of 25 degrees C, HMF could be completely converted to 2,5-bis(hydroxymethyl)furan (BHMF) in a good yield of 94% after 2 h. Moreover, a plausible reaction mechanism was speculated, where siloxane in situ formed via hydrosilylation was found to be the key species responsible for the high reactivity.

引用

页数：12

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