cis,trans-dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]-ruthenium(II)

被引：5

作者：

Oyama, Dai ^{[1
]}

Hamada, Takashi ^{[2
]}

机构：

[1] Fukushima Univ, Dept Ind Syst Engn, Cluster Sci & Technol, Fukushima 9601296, Japan

[2] Fukushima Univ, Fac Educ, Dept Sci Educ, Fukushima 9601296, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808003188

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [RuCl2(C13H9N3)-(CO)(2)], consists of four crystallographically independent Ru-II complexes. Each RuII atom is in a distorted octahedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short interatomic distances (2.60-2.67 angstrom) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor-acceptor interaction between the pynp and carbonyl ligands.

引用

页码：M442 / U99

页数：18