Diffusion behavior and distribution regulation of MgO in MgO-bearing pellets

被引:12
作者
Gao, Qiang-jian [1 ]
Shen, Yan-song [2 ]
Wei, Guo [1 ]
Jiang, Xin [1 ]
Shen, Feng-man [1 ]
机构
[1] Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
[2] Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
magnesia; iron oxide; ore pellets; diffusion; distribution; BLAST-FURNACE; SWELLING BEHAVIOR; OXIDIZED PELLET; RAW-MATERIALS; REDUCTION; OLIVINE; GAS;
D O I
10.1007/s12613-016-1318-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, the diffusion behavior between MgO and Fe2O3 (the main iron oxide in pellets) is investigated using a diffusion couple method. In addition, the distribution regulation of MgO in MgO-bearing pellets is analyzed via pelletizing experiments. The results illustrate that MgO is prone to diffuse into Fe2O3 in the form of solid solution; the diffusion rate considered here is 13.64 A mu m center dot min(-1). Most MgO content distributes in the iron phase instead of the slag phase. The MF phase {(Mg1-x Fe-x)O center dot Fe2O3, x aecurrency sign 1} is generated in the MgO-bearing pellets. However, the distribution of MgO in the radial direction of the pellets is inconsistent. The solid solution portion of MgO in the MF phase is larger in the outer layer of the pellets than in the inner layer. In this work, the approximate chemical composition of the MF phase in the outer layer of the pellets is {(Mg0.35-0.77 center dot Fe0.65-0.23) O center dot Fe2O3} and in the inner layer is {(Mg0.13-0.45 center dot Fe0.87-0.55) O center dot Fe2O3}.
引用
收藏
页码:1011 / 1018
页数:8
相关论文
共 24 条
[1]  
Biswas A.K., 1981, PRINCIPLES BLAST FUR, P38
[2]   Influence of sulfur content in raw materials on oxidized pellets [J].
Chun Tie-jun ;
Zhu De-qing ;
Pan Jian .
JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY, 2011, 18 (06) :1924-1929
[3]  
EISENHUETTENLEUT V D, 1995, SLAG ATLAS, P70
[4]  
Fu J.Y., 2005, BASIC PRINCIPLES TEC, P336
[5]  
Gao Q.J., 2012, 4 AUSTR CHIN JAP S I, P102
[6]   Characteristics of Calcined Magnesite and Its Application in Oxidized Pellet Production [J].
Gao, Qiang-jian ;
Wei, Guo ;
Jiang, Xin ;
Zheng, Hai-yan ;
Shen, Feng-man .
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL, 2014, 21 (04) :408-412
[7]   Gas-solid reduction kinetic model of MgO-fluxed pellets [J].
Gao, Qiang-jian ;
Shen, Feng-man ;
Jiang, Xin ;
Wei, Guo ;
Zheng, Hai-yan .
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2014, 21 (01) :12-17
[8]   Effects of MgO Containing Additive on Low-Temperature Metallurgical Properties of Oxidized Pellet [J].
Gao Qiang-jian ;
Shen Feng-man ;
Wei Guo ;
Jiang Xin ;
Zheng Hai-yan .
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL, 2013, 20 (07) :25-28
[9]  
[高强健 Gao Qiangjian], 2013, [东北大学学报. 自然科学版, Journal of Northeastern University. Natural Science], V34, P103
[10]   Effect of Circulating Elements on the Dynamic Reduction Swelling Behaviour of Olivine and Acid Iron Ore Pellets under Simulated Blast Furnace Shaft Conditions [J].
Iljana, Mikko ;
Mattila, Olli ;
Alatarvas, Tuomas ;
Kurikkala, Jari ;
Paananen, Timo ;
Fabritius, Timo .
ISIJ INTERNATIONAL, 2013, 53 (03) :419-426