Determination of hydrazine by polyNi(II) complex modified electrodes with a wide linear calibration range

被引:50
作者
Azad, Uday Pratap [1 ]
Ganesan, Vellaichamy [1 ]
机构
[1] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, UP, India
关键词
Chemically modified electrodes; Electropolymerization; Nafion; Hydrazine oxidation; Electrocatalysis; GLASSY-CARBON ELECTRODE; ELECTROCATALYTIC OXIDATION; AMPEROMETRIC SENSOR; ALKALINE-SOLUTIONS; HYDROGEN-PEROXIDE; NANOPARTICLES; SYSTEM; FILM; ELECTROOXIDATION; HYDROXYLAMINE;
D O I
10.1016/j.electacta.2011.04.051
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Polymeric [Ni(11)(teta)](2+) (poly(Ni); teta =C-meso-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane)) modified glassy carbon and Nafion (NO-coated glassy carbon electrodes (GC/poly(Ni) and GC/Nf/poly(Ni), respectively) were used for the efficient electrocatalytic oxidation of hydrazine (HZ) in 0.1 M NaOH. The catalytic currents were proportional to the concentration of HZ with a wide linear calibration range (LCR). GC/poly(Ni) had a LCR from 1.0 mu M to 10.0 mM, whereas that of GC/Nf/poly(Ni) ranged from 1.0 mu M to 100.0 mM. The latter is the widest LCR reported to date. The presence of the Nf film (i.e., in GC/Nf/poly(Ni)) not only increased the stability of the poly(Ni) film but also widened the LCR. The electrocatalytic oxidation of HZ obeyed first-order kinetics with respect to HZ concentration. The kinetic parameters were investigated by cyclic voltammetry and chronoamperometry. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5766 / 5770
页数:5
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