High-valent organometallic copper and palladium in catalysis

被引：722
作者：
Hickman, Amanda J. [1 ]
Sanford, Melanie S. [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
NATURE | 2012年 / 484卷 / 7393期
基金：
美国国家科学基金会;
关键词：
C-H ACTIVATION; CROSS-COUPLING REACTIONS; X-RAY-STRUCTURE; REDUCTIVE-ELIMINATION; BOND-FORMATION; CONJUGATE ADDITION; OXIDATIVE-ADDITION; SUBSTITUTION-REACTIONS; TERMINAL ALKYNES; ARYL;
D O I：
10.1038/nature11008
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Copper and palladium catalysts are critically important in numerous commercial chemical processes. Improvements in the activity, selectivity and scope of these catalysts could drastically reduce the environmental impact, and increase the sustainability, of chemical reactions. One rapidly developing strategy for achieving these goals is to use 'high-valent' organometallic copper and palladium intermediates in catalysis. Here we describe recent advances involving both the fundamental chemistry and the applications of these high-valent metal complexes in numerous synthetically useful catalytic transformations.
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收藏
页码：177 / 185
页数：9
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