A N-aryloxy-β-diketiminate ligand in 4d, 4f and 5f-metals complexes

被引：28

作者：

Dulong, Florian ^{[1
]}

Bathily, Oumou ^{[1
]}

Thuery, Pierre ^{[1
]}

Ephritikhine, Michel ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] CEA Saclay, CNRS UMR 3299, SIS2M, IRAMIS,CEA, F-91191 Gif Sur Yvette, France

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 39期

关键词：

CATALYTIC APPLICATIONS; ZINC-COMPLEXES; REACTIVITY; CHEMISTRY; COPOLYMERIZATION; POLYMERIZATION; ACTIVATION; PRECURSORS; CHLORIDES; CHELATE;

D O I：

10.1039/c2dt31220d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new class of functionalized beta-diketiminate ligands has been prepared from commercially available reagents. The novel N-aryloxy-beta-diketiminate ligand proves to be an excellent ligand to support 4d, 4f and 5f metal ions.

引用

页码：11980 / 11983

页数：4

共 31 条

[1] COMPLEXES OF N,N'-DI(2-HYDROXYETHYL)-2,4-PENTANEDIIMINE - PREPARATION AND STRUCTURE OF A COBALT(III) COMPLEX [J].

BERTRAND, JA ;

HELM, FT ;

CARPENTE.LJ .

INORGANICA CHIMICA ACTA, 1974, 9 (01) :69-75

[2] Oxidative addition to a Zirconium(IV) redox-active ligand complex [J].

Blackmore, KJ ;

Ziller, JW ;

Heyduk, AF .

INORGANIC CHEMISTRY, 2005, 44 (16) :5559-5561

[3] The chemistry of β-diketiminatometal complexes [J].

Bourget-Merle, L ;

Lappert, MF ;

Severn, JR .

CHEMICAL REVIEWS, 2002, 102 (09) :3031-3065

[4] Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials [J].

Cantat, Thibault ;

Scott, Brian L. ;

Kiplinger, Jaqueline L. .

CHEMICAL COMMUNICATIONS, 2010, 46 (06) :919-921

[5] Controlled synthesis of mononuclear or binuclear aryloxo ytterbium complexes supported by β-diketiminate ligand and their activity for polymerization of ε-caprolactone and L-lactide [J].

Chen, Hongxia ;

Liu, Peng ;

Yao, Haisheng ;

Zhang, Yong ;

Yao, Yingming ;

Shen, Qi .

DALTON TRANSACTIONS, 2010, 39 (29) :6877-6885

[6] Single-site β-diiminate zinc catalysts for the alternating copolymerization of CO2 and epoxides:: Catalyst synthesis and unprecedented polymerization activity [J].

Cheng, M ;

Moore, DR ;

Reczek, JJ ;

Chamberlain, BM ;

Lobkovsky, EB ;

Coates, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8738-8749

[7] Synthesis, structures and catalytic properties of chelating N,N′-bis(silylated) 1,2-benzenediamidozirconium(IV) chlorides [and a titanium(IV) analogue] and dimethylamides [J].

Danièle, S ;

Hitchcock, PB ;

Lappert, MF ;

Merle, PG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (01) :13-19

[8]

Deacon GB, 2001, EUR J INORG CHEM, P1505

[9] Magnesium and zinc complexes of a potentially tridentate β-diketiminate ligand [J].

Dove, AP ;

Gibson, VC ;

Marshall, EL ;

White, AJP ;

Williams, DJ .

DALTON TRANSACTIONS, 2004, (04) :570-578

[10] Electrophilic metal precursors and a beta-diimine ligand for nickel(II)- and palladium(II)-catalyzed ethylene polymerizations [J].

Feldman, J ;

McLain, SJ ;

Parthasarathy, A ;

Marshall, WJ ;

Calabrese, JC ;

Arthur, SD .

ORGANOMETALLICS, 1997, 16 (08) :1514-1516

← 1 2 3 4 →