Synthesis of Ge[N(SiMe2Ph)2]2 and crystal structures of the benzil adducts Ph2C2O2Ge[N(SiMe2Ph)2]2 and Ph2C2O2Ge[N(SiMe3)2]2

被引：5

作者：

Schrick, Aaron C. ^{[1
]}

Chen, Chao ^{[2
]}

Rheingold, Arnold L. ^{[2
]}

Weinert, Charles S. ^{[1
]}

机构：

[1] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

MAIN GROUP CHEMISTRY | 2012年 / 11卷 / 01期

基金：

美国国家科学基金会;

关键词：

Germanium; germylene; benzil; oxidative addition; GROUP-14; METAL-COMPOUNDS; C-H ACTIVATION; REACTIVITY; GERMYLENES; COMPLEXES; INSERTION; SN; GERMANIUM(II); SILYLENE; ALKANES;

D O I：

10.3233/MGC-2012-0056

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new germylene [(PhMe2Si)(2)N](2)Ge has been prepared and fully characterized, and the oxidative addition of [(PhMe2Si)(2)N](2)Ge and [(Me3Si)(2)N](2)Ge with the well-known germylene trapping reagent benzil (1,2-phenylethane-1,2-dione) has been carried out. The crystal structures of the resulting germanium(IV) benzil adducts Ph2C2O2Ge[N(SiMe2Ph)(2)](2) and Ph2C2O2Ge[N(SiMe3)(2)](2) were obtained. The two adducts are essentially isostructural and both exhibit a pseudo-tetrahedral environment at the germanium atom and a nearly planar environment at the nitrogen atoms of the bis(silyl)amido-ligands.

引用

页码：3 / 11

页数：9

共 50 条

[1] A STUDY OF A VARIETY OF O,O-ALKYLENE DITHIOPHOSPHATE DERIVATIVES OF TRIPHENYLGERMANE AND DIPHENYLGERMANE - CRYSTAL-STRUCTURES OF PH(3)GE[S(2)POCME(2)CME(2)O], PH(3)GE[S(2)POCH(2)CME(2)CH(2)O], AND PH(3)GE[S(2)POCH(2)CET(2)CH(2)O] C6H6
DRAKE, JE
MISLANKAR, AG
RATNANI, R
YANG, JC
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1995, 73 (07): : 915 - 928
[2] Synthesis and reactivity of the bulky germanium(IV) trisamide complexes BrGe[N(SiMe3)2]3 and LiGe[N(SiMe3)2]3:: X-ray crystal structures of BrGe[N(SiMe3)2]3 and [(Me3Si)2N]3Ge(CH2CH2CH2CH3)
Walding, JL
Fanwick, PE
Weinert, CS
INORGANICA CHIMICA ACTA, 2005, 358 (04) : 1186 - 1192
[3] {[Si(SiMe3)3]2Ge9-SiMe2-(C6H4)-SiMe2-Ge9[Si(SiMe3)3]2K}- : The Connection of Metalloid Clusters via an Organic Linker
Kysliak, Oleksandr
Schrenk, Claudio
Schnepf, Andreas
INORGANIC CHEMISTRY, 2017, 56 (16) : 9693 - 9697
[4] New potentially tridentate amidinate ligand {o-MeOC6H4NC(Ph)N(SiMe3)}-. Synthesis and molecular structures of amidinate complexes of lithium [{o-MeOC6H4NC(Ph)N(SiMe3)}Li]2 and yttrium [{o-MeOC6H4NC(Ph)N(SiMe3)}YCl2(THF)2]2
Rad'kov, V. Yu
Skvortsov, G. G.
Fukin, G. K.
Lyssenko, K. A.
Antipin, M. Yu
Trifonov, A. A.
RUSSIAN CHEMICAL BULLETIN, 2011, 60 (05) : 803 - 808
[5] An Electrochemical and Structural Study of the Iron Silylamides Fe[N(SiMe3)2]2 and Fe[N(SiMe3)2]3 (in German)
Margraf, Guenter
Schoedel, Frauke
Saenger, Inge
Bolte, Michael
Wagner, Matthias
Lerner, Hans-Wolfram
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2012, 67 (06): : 549 - 556
[6] Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe3)2}2 (E = Ge, Sn, Pb) and ECl{N(SiMe3)2} (E = Ge, Sn)
Cabeza, Javier A.
Reynes, Javier F.
Garcia, Felipe
Garcia-Alvarez, Pablo
Garcia-Soriano, Ruben
CHEMICAL SCIENCE, 2023, 14 (44) : 12477 - 12483
[7] Synthesis and characterization of tantalum(V) metallaheterocycle (Me2N)3(TaN(SiMe3)SiMe2C)over-barH2 and chloro-mixed-amide (Me2N)3Ta(Cl)[N(SiMe3)2]
Cai, H
Yu, XH
Chen, TN
Chen, XT
You, XZ
Xue, ZL
CANADIAN JOURNAL OF CHEMISTRY, 2003, 81 (11) : 1398 - 1405
[8] Quantitation of the THF Content in Fe[N(SiMe3)2]2 •xTHF
Broere, Daniel L. J.
Coric, Ilija
Brosnahan, Anna
Holland, Patrick L.
INORGANIC CHEMISTRY, 2017, 56 (06) : 3140 - 3143
[9] Ge(NR2)2 (R = SiMe3) insertion into LAu-Cl bonds
Anandhi, U.
Sharp, Paul R.
INORGANICA CHIMICA ACTA, 2006, 359 (11) : 3521 - 3526
[10] Ge[N(SiMe2iPr)2]2:: A new germylene and its coordination chemistry leads to the shortest Ge-Co bond
Schnepf, Andreas
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (06): : 935 - 938

← 1 2 3 4 5 →