Crystal structure of copper(II) fluoroindate(III) Cu(InF4)2•10H2O

被引:4
作者
Davidovich, R. L. [1 ]
Logvinova, V. B. [1 ]
Tkachev, V. V. [2 ]
Shilov, G. V. [2 ]
机构
[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka, Russia
关键词
synthesis; indium(III); complex fluoride; crystal structure; Cu(II); octahedron; structure type; CU3(ZRF7)2.16H2O; COMPLEXES; GALLIUM; INDIUM;
D O I
10.1134/S002247661707023X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new indium(III) fluoride complex Cu(InF4)(2)center dot 10H(2)O with the divalent Cu2+ cation is synthesized for first time, and its crystal structure, which is a new type of the structure of complex fluorides of trivalent metals with divalent cations, obtained from a hydrofluoric acid solution, is studied. The structure of Cu(InF4)(2)center dot 10H(2)O is monoclinic, space group P2(1)/a. The structure is formed by isolated centrosymmetric distorted octahedral complex [Cu(H2O)(6)](2+) cations and isolated distorted octahedral complex [InF4(H2O)(2)](-) anions with the cis arrangement of coordinated water molecules. The branched system of O-H center dot F hydrogen bonds, which is formed by the coordinated H2O molecules with the F atoms of anions, combines the structural elements of the compound to form a three-dimensional framework.
引用
收藏
页码:1436 / 1439
页数:4
相关论文
共 18 条
  • [1] STRUCTURAL CHEMISTRY OF COMPOUNDS CS[MF4(H2O)2] (M = AL, CR, MN, FE)
    BENTRUP, U
    MASSA, W
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 593 (02): : 207 - 216
  • [2] Complexes of aluminium, gallium and indium trifluorides with neutral oxygen donor ligands: Synthesis, properties and reactions
    Bhalla, Rajiv
    Burt, Jennifer
    Hector, Andrew L.
    Levason, William
    Luthra, Sajinder K.
    McRobbie, Graeme
    Monzittu, Francesco M.
    Reid, Gillian
    [J]. POLYHEDRON, 2016, 106 : 65 - 74
  • [3] SYNTHESIS AND CRYSTAL-STRUCTURE OF CESIUM DIAQUATETRAFLUOROMANGANATE(III)
    BUKOVEC, P
    KAUCIC, V
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09): : 945 - 947
  • [4] Bukvetskii B. V., 1977, KOORDINATS KHIM, V3, P926
  • [5] Bukvetskii B.V., 1976, Koord. Khim, V2, P1129
  • [6] Bukvetskii B. V., 1976, KOORDINATS KHIM, V2, p[423, 424]
  • [7] CHERNAYA TS, 1983, KRISTALLOGRAFIYA+, V28, P667
  • [8] Crystal structure of rubidium and cesium tetrafluoroindate(III) dihydrates
    Davidovich, R. L.
    Logvinova, V. B.
    Tkachev, V. V.
    Shilov, G. V.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 58 (04) : 813 - 816
  • [9] Davidovich R. L., 1976, ATLAS DERIVATOGRAMS
  • [10] SYNTHESIS, CRYSTAL-STRUCTURE AND THERMAL DEHYDRATION OF CSMNF4 2H2O
    DUBLER, E
    LINOWSKY, L
    MATTHIEU, JP
    OSWALD, HR
    [J]. HELVETICA CHIMICA ACTA, 1977, 60 (05) : 1589 - 1600