Dipole polarizability for confined two-electron atomic systems: simple approximations

被引:7
作者
Montgomery, H. E., Jr. [1 ]
Pupyshev, Vladimir, I [2 ]
机构
[1] Ctr Coll Danville, Chem Program, Danville, KY 40444 USA
[2] Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia
关键词
confined systems; helium atom; dipole polarizability; Kirkwood approximation; Buckingham approximation; GROUND-STATE; HELIUM; POLARIZATION; ENERGY;
D O I
10.1088/1402-4896/ab45a1
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The electric dipole polarizability is analyzed for a two-electron system embedded in an impenetrable spherically symmetric cavity. Methods to find simple estimates of polarizability and corrections to them are considered. The expressions for matrix elements in Hylleraas coordinates required for energy and polarizability variational calculations are presented for the two-electron atomic system. The results of simple polarizability estimates are presented for the ground state of the helium atom and are compared with polarizabilities calculated using Hylleraas variational perturbation theory and with recently calculated polarizabilities reported in the literature for confined systems.
引用
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页数:11
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