New generation Amberlite XAD resin for the removal of metal ions: A review

被引:82
作者
Ahmad, Akil [1 ]
Siddique, Jamal Akhter [2 ]
Laskar, Mohammad Asaduddin [3 ]
Kumar, Rajeev [4 ]
Mohd-Setapar, Siti Hamidah [1 ]
Khatoon, Asma [1 ]
Shiekh, Rayees Ahmad [5 ]
机构
[1] Univ Teknol Malaysia, Fac Chem Engn, CLEAR, Utm Johor Bahru 81310, Johor, Malaysia
[2] Czech Tech Univ, Fac Civil Engn, Dept Mat Engn & Chem, Prague 716629, Thakurova, Czech Republic
[3] Jazan Univ, Dept Chem, Jazan, Saudi Arabia
[4] King Abdulaziz Univ, Fac Meteorol Environm & Arid Land Agr, Dept Environm Sci, Jeddah 21589, Saudi Arabia
[5] Taibah Univ, Fac Sci, Dept Chem, Al Madinah Al Munawarrah, Saudi Arabia
来源
JOURNAL OF ENVIRONMENTAL SCIENCES | 2015年 / 31卷
关键词
Amberlite XAD; Toxic metals; Chelating resin; Preconcentration; Sorption capacity; SOLID-PHASE EXTRACTION; ATOMIC-ABSORPTION-SPECTROMETRY; ONLINE PRECONCENTRATION SYSTEM; PLASMA-MASS SPECTROMETRY; RARE-EARTH-ELEMENTS; TRACE HEAVY-METALS; ENVIRONMENTAL-SAMPLES; WATER SAMPLES; SPECTROPHOTOMETRIC DETERMINATION; FUNCTIONALIZED RESIN;
D O I
10.1016/j.jes.2014.12.008
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The direct determination of toxic metal ions, in environmental samples, is difficult because of the latter's presence in trace concentration in association with complex matrices, thereby leading to insufficient sensitivity and selectivity of the methods used. The simultaneous removal of the matrix and preconcentration of the metal ions, through solid phase extraction, serves as the promising solution. The mechanism involved in solid phase extraction (SPE) depends on the nature of the sorbent and analyte. Thus, SPE is carried out by means of adsorption, ion exchange, chelation, ion pair formation, and so forth. As polymeric supports, the commercially available Amberlite resins have been found very promising for designing chelating matrices due to its good physical and chemical properties such as porosity, high surface area, durability and purity. This review presents an overview of the various works done on the modification of Amberlite XAD resins with the objective of making it an efficient sorbent. The methods of modifications which are generally based on simple impregnation, sorption as chelates and chemical bonding have been discussed. The reported results, including the preconcentration limit, the detection limit, sorption capacity, preconcentration factors etc., have been reproduced. (C) 2015 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.
引用
收藏
页码:104 / 123
页数:20
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