A pillar[5]arene-based supramolecular polymer network gel and its application in adsorption and removal of organic dye in water

被引:5
作者
An, Jun-Nian [1 ]
Qu, Wen-Juan [1 ]
Zhang, Qin-Peng [1 ]
Ma, Xiao-Qiang [1 ]
Zhu, Wen-Bo [1 ]
Zhang, You-Ming [1 ,2 ]
Yao, Hong [1 ]
Lin, Qi [1 ]
Wei, Tai-Bao [1 ]
机构
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecoenvironm Related Polymer Mat, Key Lab Polymer Mat Gansu Prov,Minist Educ China, Lanzhou 730070, Gansu, Peoples R China
[2] Lanzhou City Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
Supramolecular polymer gel; Pillar[5]arene; Host-guest; Dye removal; HOST-GUEST INTERACTIONS; FLUORESCENCE; RECOGNITION; COORDINATION; HYDROGEL; MOTIFS; PHOTO;
D O I
10.1007/s10847-020-01000-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel 3D supramolecular polymer network gel (DP5G) was successfully constructed by easy to synthesize tripodal guest (SZ) and thioacetylhydrazone functionalized di-pillar[5]arene host (DP5). Interestingly, the DP5G showed aggregation induced emission (AIE). Moreover, the DP5G displayed a 3D network structure, which was used to dye removal experiments. Notably, the xerogel DP5G could effectively remove cationic dyes (including crystal violet and rhodamine B) from aqueous solution and the removal percentages are 96.3% and 95.4%, respectively. In addition, the maximal adsorption capacity of DP5G towards crystal violet and rhodamine B are 19.65 mg/g and 22.85 mg/g, respectively. The stability of the 3D supramolecular polymer network gel (DP5G) was further investigated, which exhibited excellent stability toward outer stimuli such as pH, competitive agents, oxidant and reducing agent.
引用
收藏
页码:137 / 145
页数:9
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