Chiral sulfoxides in asymmetric synthesis: Enantioselective synthesis of (-)-(5S,7R)-tarchonanthuslactone

被引：45

作者：

Solladie, G

GressotKempf, L

机构：

[1] Univ. Louis Pasteur (ECPM), Lab. de Stereochimie Associe au CNRS, 67008 - Strasbourg

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 08期

关键词：

D O I：

10.1016/0957-4166(96)00292-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enantioselective synthesis of (-)-(5S, 7R)-Tarchonanthuslactone, a substituted delta-lactone isolated from a compositae, is described. The main feature of this short synthesis is the stereoselective reduction of a beta,delta-diketosulfoxide affording in 6 steps the chiral central part of the molecule, a syn-1,3-diol unit. Copyright (C) 1996 Elsevier Science Ltd

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页码：2371 / 2379

页数：9

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