Vanadium complexes immobilized on solid supports and their use as catalysts for oxidation and functionalization of alkanes and alkenes

被引：156

作者：

Maurya, Mannar R. ^{[1
]}

Kumar, Amit ^{[2
]}

Pessoa, J. Costa ^{[2
]}

机构：

[1] Indian Inst Technol, Dept Chem, Roorkee 247667, Uttar Pradesh, India

[2] Univ Tecn Lisboa, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

来源：

COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 19-20期

关键词：

Supported vanadium complexes; Polymer-support; Zeolite-Y encapsulated complexes; MCM-supported complexes; Catalysts; Organic transformations; SCHIFF-BASE COMPLEXES; LIQUID-PHASE HYDROXYLATION; METHYL PHENYL SULFIDE; ENCAPSULATED METAL-COMPLEXES; OXYGEN-ATOM TRANSFER; ZEOLITE-Y; COPPER(II) COMPLEXES; HYDROGEN-PEROXIDE; MOLECULAR-SIEVES; OXOVANADIUM(IV) COMPLEXES;

D O I：

10.1016/j.ccr.2011.01.050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review mainly discusses the immobilization strategies that have been used for vanadium complexes, typically mesoporous material, zeolites and polymers, the characterization procedures for the obtained materials, and their catalytic applications. The retention of the active metal compound within the catalyst may be based on (i) adsorption, (ii) the formation of covalent bonds between metal ligand and support,(iii) ion exchange, (iv) encapsulation, or (v) entrapment. The heterogenized complexes are used as catalysts for oxidations and functionalization of alkanes, alkenes and other substrates, and an account of the various applications reported is given. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：2315 / 2344

页数：30

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