Coordination polymers with a pyridyl-salen ligand for photocatalytic carbon dioxide reduction

被引:30
作者
Liu, Yi [1 ]
Guo, Jin-Han [1 ]
Dao, Xiao-Yao [1 ]
Zhang, Xiu-Du [1 ]
Zhao, Yue [1 ]
Sun, Wei-Yin [1 ]
机构
[1] Nanjing Univ, Coordinat Chem Inst, State Key Lab Coordinat Chem,Collaborat Innovat C, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210023, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC-FRAMEWORK; ELECTROCHEMICAL REDUCTION; ARTIFICIAL PHOTOSYNTHESIS; CO2; REDUCTION; MOF; COMPLEXES; CATALYSIS; PHOTOREDUCTION; CONVERSION; NANOSHEETS;
D O I
10.1039/d0cc00425a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new ligand H2L with pyridine and salen moieties and its coordination polymers (CPs) [Mn(L)Cl]center dot DMF (1) and [Fe(L)Cl]center dot DMF (2) were synthesized and their photocatalytic activity for the conversion of CO2 into CO under visible-light irradiation was investigated. This is the first instance of pyridyl-salen-ligand based CPs for photocatalyzing CO2 reduction.
引用
收藏
页码:4110 / 4113
页数:4
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