Thermal properties of cis-1,4-poly(butadiene)

被引：18

作者：

Janowska, G ^{[1
]}

Slusarski, L ^{[1
]}

机构：

[1] Lodz Tech Univ, Inst Polymers, PL-90924 Lodz, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2001年 / 65卷 / 01期

关键词：

DTA; DTA-MS; DSC; elastomer; polybutadiene; TG; TG-FTIR; TG-MS; thermal properties; thermal stability;

D O I：

10.1023/A:1011545122518

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal properties of cis-1,4-poly(butadiene), Europrene cis, were investigated by means of thermal analysis and complementary methods. Thermal analysis of polymer was carried out both in air and inert atmosphere with a derivatgraph, DSC and internal TG-FTIR coupling system as well as internal TG, DTA-MS coupling system. It was found that investigations in air atmosphere the method of the sample preparation of cis-1,4-poly(butadiene) influences the results of thermal analysis, which is connected with the rate oxygen diffusion into the reaction zone. Taking into consideration both the method of the sample preparing and atmosphere of thermal studies, the values of activation energy of destruction of cis-1,4-poly(butadiene) were determined. Using TG-FTIR and TG-MS methods, some products of thermal destruction of elastomer were determined.

引用

页码：205 / 212

页数：8

共 50 条

[31] Thermal resistance and dynamic damping properties of poly (styrene-butadiene-styrene)/thermoplastic polyurethane composites elastomer material
Wu, Jyh-Horng
Li, Chia-Hao
Wu, Yao-Tsu
Leu, Ming-Tsong
Tsai, Yuhsin
COMPOSITES SCIENCE AND TECHNOLOGY, 2010, 70 (08) : 1258 - 1264
[32] Realistic Coarse-Grain Model of cis-1,4-Polybutadiene: From Chemistry to Rheology
Kempfer, K.
Devemy, J.
Dequidt, A.
Couty, M.
Malfreyt, P.
MACROMOLECULES, 2019, 52 (07) : 2736 - 2747
[33] Thermal Annealing of High cis-1,4-Polybutadiene/Octadecyl Acrylate Blends as a One-Step Process for Fabricating Shape Memory Polymers
Basak, Sayan
Angel, Juan Camilo Marin
Cavicchi, Kevin A.
ACS APPLIED POLYMER MATERIALS, 2023, 5 (07) : 4738 - 4752
[34] NOVEL POLYMERIC STRUCTURES VIA THE CHLORINATION OF CIS-1,4-POLYBUTADIENE IN THE PRESENCE OF ARYL NUCLEOPHILES
HAHN, SF
DREYFUSS, MP
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (12) : 3039 - 3047
[35] Interaction of sulphur-vulcanised elastomer based on cis-1,4-polybutadiene with nitric acid
Tsaikova, S
Stoeva, S
Tsaikov, P
Georgiev, T
OXIDATION COMMUNICATIONS, 2006, 29 (01): : 162 - 171
[36] High cis-1,4 polyisoprene or cis-1,4/3,4 binary polyisoprene synthesized using 2-(benzimidazolyl)-6-(1-(arylimino)ethyl)pyridine cobalt(II) dichlorides
He, Aihua
Wang, Geng
Zhao, Weizhen
Jiang, Xiubo
Yao, Wei
Sun, Wen-Hua
POLYMER INTERNATIONAL, 2013, 62 (12) : 1758 - 1766
[37] Synthesis and characterization of model diblock copolymers of poly(dimethylsiloxane) with poly(1,4-butadiene) or poly(ethylene)
Ciolino, A
Sakellariou, G
Pantazis, D
Villar, MA
Vallés, E
Hadjichristidis, N
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (05) : 1579 - 1590
[38] Synthesis and characterization of trans-1,4-butadiene/isoprene copolymers: Determination of sequence distribution and thermal properties
Xiu-bo Jiang
Qing-fei Zhang
Ai-hua He
Chinese Journal of Polymer Science, 2015, 33 : 815 - 822
[39] Synthesis and characterization of trans-1,4-butadiene/isoprene copolymers: Determination of sequence distribution and thermal properties
Jiang, Xiu-bo
Zhang, Qing-fei
He, Ai-hua
CHINESE JOURNAL OF POLYMER SCIENCE, 2015, 33 (06) : 815 - 822
[40] Poly(1,4-cyclohexylenedimethylene 1,4-cyclohexanedicarboxylate): Influence of stereochemistry of 1,4-cyclohexylene units on the thermal properties
Berti, Corrado
Binassi, Enrico
Celli, Annamaria
Colonna, Martino
Fiorini, Maurizio
Marchese, Paola
Marianucci, Elisabetta
Gazzano, Massimo
Di Credico, Francesco
Brunelle, Daniel J.
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2008, 46 (06) : 619 - 630

← 1 2 3 4 5 →