Elucidation of the reaction mechanism for the palladium-catalyzed synthesis of vinyl acetate

被引：61
作者：
Stacchiola, D
Calaza, F
Burkholder, L
Schwabacher, AW
Neurock, M
Tysoe, WT [1 ]
机构：
[1] Univ Wisconsin, Dept Chem & Biochem, Milwaukee, WI 53211 USA
[2] Univ Wisconsin, Surface Studies Lab, Milwaukee, WI 53211 USA
[3] Univ Virginia, Dept Chem Engn, Charlottesville, VA 22904 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 29期
关键词：
IR spectroscopy; isotopes; palladium; reaction mechanisms; surface chemistry;
D O I：
10.1002/anie.200500782
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Finding the right pathway: Reaction of isotopomers of ethylene with acetate species (see scheme) adsorbed on a Pd(111) surface in ultrahigh vacuum has shown that vinyl acetate is produced by insertion of ethylene into the acetate species to form an acetoxyethyl intermediate, which decomposes by β-hydride elimination to yield vinyl acetate. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4572 / 4574
页数：3
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