Lactide-derived monomers for radical thiocarbonyl addition ring-opening copolymerisation

被引：16

作者：

Ivanchenko, Oleksandr ^{[1
]}

Mazieres, Stephane ^{[1
]}

Harrisson, Simon ^{[2
]}

Destarac, Mathias ^{[1
]}

机构：

[1] Univ Paul Sabatier, Lab IMRCP, CNRS UMR 5623, 118 Route Narbonne, F-31062 Toulouse, France

[2] Univ Bordeaux, LCPO, ENSCBP, CNRS UMR 5623, 16 Ave Pey Berland, F-33607 Pessac, France

来源：

POLYMER CHEMISTRY | 2022年 / 13卷 / 39期

关键词：

DEGRADABLE VINYL-POLYMERS; POLYMERIZATION; CAPROLACTONE; DESIGN;

D O I：

10.1039/d2py00893a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The six-membered dl-thionolactide and dl-dithionolactide are reactive in radical ring-opening copolymerisation with a series of vinyl monomers to yield chemically degradable polymers. Bleach is an excellent degrading agent for both thioester and thioacetal linkages compared to classical nucleophilic treatment with amines.

引用

收藏

页码：5525 / 5529

页数：5

相关论文

共 23 条

[1] FREE-RADICAL RING-OPENING POLYMERIZATION OF 4,7-DIMETHYL-2-METHYLENE-1,3-DIOXEPANE AND "5,6-BENZO-2-METHYLENE-1,3-DIOXEPANE [J].

BAILEY, WJ ;

NI, Z ;

WU, SR .

MACROMOLECULES, 1982, 15 (03) :711-714

[2] SYNTHESIS OF POLY-EPSILON-CAPROLACTONE VIA A FREE-RADICAL MECHANISM - FREE-RADICAL RING-OPENING POLYMERIZATION OF 2-METHYLENE-1,3-DIOXEPANE [J].

BAILEY, WJ ;

NI, Z ;

WU, SR .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (11) :3021-3030

[3] Controlling the synthesis of degradable vinyl polymers by xanthate-mediated polymerization [J].

Bell, Craig A. ;

Hedir, Guillaume G. ;

O'Reilly, Rachel K. ;

Dove, Andrew P. .

POLYMER CHEMISTRY, 2015, 6 (42) :7447-7454

[4] Thiocarbonyl chemistry in polymer science [J].

Bingham, Nathaniel M. ;

Abousalman-Rezvani, Zahra ;

Collins, Kyle ;

Roth, Peter J. .

POLYMER CHEMISTRY, 2022, 13 (20) :2880-2901

[5] Thioester-Functional Polyacrylamides: Rapid Selective Backbone Degradation Triggers Solubility Switch Based on Aqueous Lower Critical Solution Temperature/Upper Critical Solution Temperature [J].

Bingham, Nathaniel M. ;

Nisa, Qamar Un ;

Chua, Sophie H. L. ;

Fontugne, Lea ;

Spick, Matt P. ;

Roth, Peter J. .

ACS APPLIED POLYMER MATERIALS, 2020, 2 (08) :3440-3449

[6] Degradable vinyl copolymers through thiocarbonyl addition-ring-opening (TARO) polymerization [J].

Bingham, Nathaniel M. ;

Roth, Peter J. .

CHEMICAL COMMUNICATIONS, 2019, 55 (01) :55-58

[7] Vinyl copolymers with faster hydrolytic degradation than aliphatic polyesters and tunable upper critical solution temperatures [J].

Bossion, Amaury ;

Zhu, Chen ;

Guerassimoff, Lea ;

Mougin, Julie ;

Nicolas, Julien .

NATURE COMMUNICATIONS, 2022, 13 (01)

[8]

Delplace V, 2015, NAT CHEM, V7, P771, DOI [10.1038/NCHEM.2343, 10.1038/nchem.2343]

[9] One-Step Synthesis of Degradable Vinylic Polymer-Based Latexes via Aqueous Radical Emulsion Polymerization [J].

Galanopoulo, Paul ;

Gil, Noemie ;

Gigmes, Didier ;

Lefay, Catherine ;

Guillaneuf, Yohann ;

Lages, Maelle ;

Nicolas, Julien ;

Lansalot, Muriel ;

D'Agosto, Franck .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (15)

[10] ε-Thionocaprolactone: an accessible monomer for preparation of degradable poly(vinyl esters) by radical ring-opening polymerization [J].

Ivanchenko, Oleksandr ;

Authesserre, Ugo ;

Coste, Guilhem ;

Mazieres, Stephane ;

Destarac, Mathias ;

Harrisson, Simon .

POLYMER CHEMISTRY, 2021, 12 (13) :1931-1938