Reactive thermoresponsive copolymer scaffolds

被引：32

作者：

Murray, Benjamin S. ^{[1
]}

Jackson, Alexander W. ^{[1
]}

Mahon, Clare S. ^{[1
]}

Fulton, David A. ^{[1
]}

机构：

[1] Newcastle Univ, Chem Nanosci Lab, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 45期

基金：

英国工程与自然科学研究理事会;

关键词：

RESPONSIVE POLYMERS; TUNABLE LCST; METHACRYLATES; WATER; POLYMERIZATION; LIBRARIES; POINT;

D O I：

10.1039/c0cc03856c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermoresponsive copolymer scaffolds containing reactive aldehyde functions were prepared and a selection of organic residues conjugated to these copolymer scaffolds through oxime/hydrazone formation. The conjugation of hydrophobic residues affords copolymers whose lower solution critical temperatures are in most cases higher than that of the parent copolymer scaffold.

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收藏

页码：8651 / 8653

页数：3

相关论文

共 15 条

[1] Stimuli responsive polymers for biomedical applications [J].

Alarcón, CDH ;

Pennadam, S ;

Alexander, C .

CHEMICAL SOCIETY REVIEWS, 2005, 34 (03) :276-285

[2] ALDEHYDE METHACRYLATES DERIVED FROM HYDROXYBENZALDEHYDES [J].

ANTONUCCI, JM .

JOURNAL OF DENTAL RESEARCH, 1978, 57 (03) :500-505

[3] Libraries of Methacrylic Acid and Oligo(ethylene glycol) Methacrylate Copolymers with LCST Behavior [J].

Becer, C. Remzi ;

Hahn, Sabine ;

Fijten, Martin W. M. ;

Thijs, Hanneke M. L. ;

Hoogenboom, Richard ;

Schubert, Ulrich S. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (21) :7138-7147

[4] Thermo-Responsive Polyoxazolines with Widely Tuneable LCST [J].

Diehl, Christina ;

Schlaad, Helmut .

MACROMOLECULAR BIOSCIENCE, 2009, 9 (02) :157-161

[5] Thermosensitive water-soluble copolymers with doubly responsive reversibly interacting entities [J].

Dimitrov, Ivaylo ;

Trzebicka, Barbara ;

Muller, Axel H. E. ;

Dworak, Andrzej ;

Tsvetanov, Christo B. .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (11) :1275-1343

[6] Dynamic combinatorial libraries constructed on polymer scaffolds [J].

Fulton, David A. .

ORGANIC LETTERS, 2008, 10 (15) :3291-3294

[7] Anionic polymerizations of oligo(ethylene glycol) alkyl ether methacrylates:: Effect of side chain length and ω-alkyl group of side chain on cloud point in water [J].

Ishizone, Takashi ;

Seki, Akiko ;

Hagiwara, Mamoru ;

Han, Seok ;

Yokoyama, Hideaki ;

Oyane, Ayako ;

Deffieux, Alain ;

Carlotti, Stephane .

MACROMOLECULES, 2008, 41 (08) :2963-2967

[8] Polymerization of oligo(ethylene glycol) (meth)acrylates: Toward new generations of smart biocompatible materials [J].

Lutz, Jean-Francois .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (11) :3459-3470

[9] Point by point comparison of two thermosensitive polymers exhibiting a similar LCST:: Is the age of poly(NIPAM) over? [J].

Lutz, Jean-Francois ;

Akdemir, Oezguer ;

Hoth, Ann .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (40) :13046-13047

[10] Ion-sensitive "isothermal" responsive polymers prepared in water [J].

Magnusson, Johannes Pall ;

Khan, Adnan ;

Pasparakis, George ;

Saeed, Aram Omer ;

Wang, Wenxin ;

Alexander, Cameron .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10852-+