Acceptor power of cations in donor - Acceptor interactions

被引：2
作者：
Buchikhin, E. P.
Chekmarev, A. M.
Kuznetsov, A. Yu.
Bobyrenko, N. A.
机构：
[1] All Russia Res Inst Chem Technol, Moscow 115409, Russia
[2] Mendeleev Russian Univ Chem Engn, Moscow, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 07期
关键词：
D O I：
10.1134/S1070363207070018
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Published data concerning quantitative evaluation of the reactivity of cations in donor-acceptor interactions were analyzed. The "relative acceptor numbers" of C degrees(2+), Mn2+, Ni2+, Al3+, and Ga3+ were determined polarographically: 2.16 +/- 0.32, 2.25 +/- 0.23, similar to 1.70, 2.35 +/- 0.27, and 2.42 +/- 0.21, respectively. The known "relative acceptor numbers" for 21 cations were systematized, and a linear correlation between the ionization potentials and "relative acceptor numbers" of "hard" cations was revealed.
引用
收藏
页码：1141 / 1147
页数：7
相关论文
共 35 条
[1]  
AZZAM AM, 1954, ELEKTROCHEM, V56, P889
[2]  
BURGER K, 1984, SOLVATION IONIC COMP, P21
[3]  
CHEKMAREV AM, 2004, SOLVOMETALLURGIYA PE
[4]   A DOUBLE-SCALE EQUATION FOR CORRELATING ENTHALPIES OF LEWIS ACID-BASE INTERACTIONS [J].
DRAGO, RS ;
WAYLAND, BB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (16) :3571-&
[5]  
ENTELIS VT, 1973, KINETIKA REAKTSII ZH, P103
[6]  
GRINBERG AA, 1952, IAN SSSR KH, P211
[7]  
GUTMANN V, 1969, MONATSH CHEM, V100, P1564
[8]  
GUTMANN V, 1971, COORDINATION CHEM NO, P29
[9]  
IOGANSEN AV, 1981, VODORODNAYASVYAZ, P123
[10]  
JAKUSZEWSKI B, 1978, ROCZN CHEM, V36, P329
1234