Synthesis and Thermolysis of the Phosphorus-Rich Manganese(I) Complex [Mn2(μ-Br){cyclo-(P4tBu3)PtBu}(CO)6]: From Complexes to Metal Phosphides

被引：10
作者：
Kircali, Aslihan [1 ]
Frank, Rene [1 ]
Gomez-Ruiz, Santiago [1 ]
Kirchner, Barbara [2 ]
Hey-Hawkins, Evamarie [1 ]
机构：
[1] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany
[2] Univ Leipzig, Wilhelm Ostwald Inst Phys & Theoret Chem, D-04103 Leipzig, Germany
来源：
CHEMPLUSCHEM | 2012年 / 77卷 / 05期
关键词：
density functional calculations; manganese; P ligands; phosphorus; rearrangement; thermolysis; IHR REAKTIVES VERHALTEN; TETRA-TERT-BUTYLCYCLOPENTAPHOSPHANIDE; X-RAY-DIFFRACTION; MOLECULAR-STRUCTURE; REACTIVE PROPERTIES; MAGNETIC-PROPERTIES; CARBONYL-COMPLEXES; ALKALI METAL; CHEMISTRY; PHOSPHORVERBINDUNGEN;
D O I：
10.1002/cplu.201200013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A complex matter: Na[cyclo-(P 5tBu 4)] reacts with two equivalents of [MnBr(CO) 5] to give the phosphorus-rich manganese(I) complex [Mn 2(μ-Br)-{cyclo-(P 4tBu 3)PtBu}(CO) 6] (see structure) containing a [{cyclo-(P 4tBu 3)}PtBu]-ligand. The rearrangement of [cyclo-(P 5tBu 4)]- to [cyclo-(P 4tBu 3)PtBu]- was rationalized by theoretical studies. Thermolysis of up to 1000°C gives Mn 2P. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：341 / 344
页数：4
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