Calixarene-Based Nanoscale Coordination Cages

被引:209
作者
Liu, Mei [1 ,3 ]
Liao, Wuping [1 ]
Hu, Chunhua [2 ]
Du, Shangchao [1 ,3 ]
Zhang, Hongjie [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] NYU, Dept Chem, New York, NY 10003 USA
[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
cage compounds; calixarenes; cobalt; crystal engineering; tripodal ligands; METAL-ORGANIC FRAMEWORKS; RETICULAR SYNTHESIS; SORPTION PROPERTIES; TRANSITION-METAL; MOLECULAR CAGE; POLYHEDRA; LIGAND; CHEMISTRY; CAPSULES; CAVITAND;
D O I
10.1002/anie.201106732
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecular shuttlecocks: The introduction of tripodal ternary acids (red; see picture) to the cobalt/calixarene (green) systems led to the formation of four unprecedented calixarene-based nanoscale coordination cages through a [6+8] condensation. The overall periphery diameters of the nanocages ranged from 3.3 to 4.7 nm, and there were two sizes for the internal cavities (1.1 and 1.7 nm). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1585 / 1588
页数:4
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