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Calixarene-Based Nanoscale Coordination Cages
被引:209
作者:
Liu, Mei
[1
,3
]
Liao, Wuping
[1
]
Hu, Chunhua
[2
]
Du, Shangchao
[1
,3
]
Zhang, Hongjie
[1
]
机构:
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] NYU, Dept Chem, New York, NY 10003 USA
[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
基金:
中国国家自然科学基金;
关键词:
cage compounds;
calixarenes;
cobalt;
crystal engineering;
tripodal ligands;
METAL-ORGANIC FRAMEWORKS;
RETICULAR SYNTHESIS;
SORPTION PROPERTIES;
TRANSITION-METAL;
MOLECULAR CAGE;
POLYHEDRA;
LIGAND;
CHEMISTRY;
CAPSULES;
CAVITAND;
D O I:
10.1002/anie.201106732
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Molecular shuttlecocks: The introduction of tripodal ternary acids (red; see picture) to the cobalt/calixarene (green) systems led to the formation of four unprecedented calixarene-based nanoscale coordination cages through a [6+8] condensation. The overall periphery diameters of the nanocages ranged from 3.3 to 4.7 nm, and there were two sizes for the internal cavities (1.1 and 1.7 nm). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:1585 / 1588
页数:4
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