Ligand-modulated ring-expansion

被引：2

作者：

Carta, Veronica ^{[1
]}

Soto, Miguel A. ^{[1
]}

MacLachlan, Mark J. ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 09期

基金：

加拿大自然科学与工程研究理事会;

关键词：

OPENING-METATHESIS POLYMERIZATION; CLOSING METATHESIS; POLYMERS; CATALYSTS; ROUTE;

D O I：

10.1039/c8cc09710k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unstrained palladium-containing macrocycle was expanded by a ring-opening metathesis strategy. This reaction was driven by coordination of a bulky ligand, 2,6-lutidine, to the palladium center, enabling a monometallic macrocycle to transform into a bimetallic dimeric macrocycle.

引用

页码：1245 / 1248

页数：4

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