Adsorption of O2 on Ag(111): Evidence of Local Oxide Formation

被引:27
作者
Andryushechkin, B. V. [1 ]
Shevlyuga, V. M. [1 ]
Pavlova, T. V. [1 ]
Zhidomirov, G. M. [1 ,2 ]
Eltsov, K. N. [1 ]
机构
[1] Russian Acad Sci, AM Prokhorov Gen Phys Inst, Ulitsa Vavilova 38, Moscow 119991, Russia
[2] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Prospect Lavrentieva 5, Novosibirsk 630090, Russia
基金
俄罗斯科学基金会;
关键词
THERMAL-DECOMPOSITION; OXYGEN; SURFACE; ATOMS; FILM;
D O I
10.1103/PhysRevLett.117.056101
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The atomic structure of the disordered phase formed by oxygen on Ag(111) at low coverage is determined by a combination of low-temperature scanning tunneling microscopy and density functional theory. We demonstrate that the previous assignment of the dark objects in STM to chemisorbed oxygen atoms is incorrect and incompatible with trefoil-like structures observed in atomic-resolution images in current work. In our model, each object is an oxidelike ring formed by six oxygen atoms around the vacancy in Ag(111).
引用
收藏
页数:5
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