Pinacol as a New Green Reducing Agent: Molybdenum- Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics

被引：87

作者：

Garcia, Nuria ^{[1
]}

Garcia-Garcia, Patricia ^{[1
]}

Fernandez-Rodriguez, Manuel A. ^{[1
]}

Rubio, Ruben ^{[1
]}

Pedrosa, Maria R. ^{[1
]}

Arnaiz, Francisco J. ^{[1
]}

Sanz, Roberto ^{[1
]}

机构：

[1] Univ Burgos, Dept Quim, Fac Ciencias, Burgos 09001, Spain

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 2-3期

关键词：

chemoselectivity; molybdenum; nitro compounds; reduction; sulfoxides; PYRIDINE N-OXIDES; NITRO-COMPOUNDS; TRANSFER HYDROGENATION; SELECTIVE REDUCTION; NITROARENES; DEOXYGENATION; EFFICIENT; COMPLEXES;

D O I：

10.1002/adsc.201100877

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions.

引用

页码：321 / 327

页数：7

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