Diastereo selective formation of a complex with an atropisomeric 4,4′-biquinazoline ligand:: The solid-state structure of cis-bis(4,4′-biquinazoline)dichloridoiridium(III) hexafluoridophosphate

被引：4

作者：

Ademi, Lumni ^{[1
]}

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

机构：

[1] Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 05期

关键词：

4,4 '-biquinazoline; chirality; iridium; diastereoselectivity; crystal structure;

D O I：

10.1016/j.inoche.2008.02.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligand 4,4'-biquinazoline (biqz) forms complexes in which it adopts either the P or M atropisomeric configuration; the complex cis-[1r(biqz)(2)Cl-2][PF6] center dot MeCN has been structurally characterised and shown to comprise a single enantionteric pair (PM-Delta)(MP-Lambda) of the six possible stereoisomers. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：564 / 567

页数：4

共 15 条

[1] Spontaneous resolution of a diastereomeric ruthenium(II) complex with an atropisomeric 4,4′-biquinazoline ligand [J].