Materials science is an interdisciplinary field applying the properties of matter to various areas of science and engineering.. In this work, the notion of the trivariate generalized multiresolution structure (TGMS) of subspace L-2 (R-3) is proposed. The characteristics of trivariate affine pseudoframes for subspaces is investigated. Construction of a GMS of Paley-Wiener subspace of L-2 (R-3) is studied. The pyramid decomposition scheme is obtained based on such a TGMS and a sufficient condition for its existence is provided. A constructive method for affine frames of L-2 (R-3) based on a TGMS is established.