Sandwich structure of a ruthenium porphyrin and an amino acid hydrazide for probing molecular chirality by circular dichroism

被引：13

作者：

Liang, Qing-Feng ^{[1
]}

Liu, Juan-Juan ^{[1
]}

Chen, Jian ^{[1
]}

机构：

[1] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 31期

基金：

中国国家自然科学基金;

关键词：

Circular Dichroism; Absolute configuration; Amino acid; Porphyrin; Sandwich structure; ABSOLUTE CONFIGURATIONAL ASSIGNMENTS; HOST-GUEST COMPLEXATION; RECOGNITION; CD; TWEEZER; DERIVATIVES; RECEPTORS;

D O I：

10.1016/j.tetlet.2011.05.081

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Owing to the strong Lewis acidity of ruthenium porphyrins, a commercial carbonyl ruthenium porphyrin and an amino acid hydrazide can assemble into a sandwich structure. The nature of such a structure is diagnostic of the absolute configuration of the amino acid by circular dichroism. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：3987 / 3991

页数：5