Sandwich structure of a ruthenium porphyrin and an amino acid hydrazide for probing molecular chirality by circular dichroism

被引：12
作者：
Liang, Qing-Feng [1 ]
Liu, Juan-Juan [1 ]
Chen, Jian [1 ]
机构：
[1] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 31期
基金：
中国国家自然科学基金;
关键词：
Circular Dichroism; Absolute configuration; Amino acid; Porphyrin; Sandwich structure; ABSOLUTE CONFIGURATIONAL ASSIGNMENTS; HOST-GUEST COMPLEXATION; RECOGNITION; CD; TWEEZER; DERIVATIVES; RECEPTORS;
D O I：
10.1016/j.tetlet.2011.05.081
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Owing to the strong Lewis acidity of ruthenium porphyrins, a commercial carbonyl ruthenium porphyrin and an amino acid hydrazide can assemble into a sandwich structure. The nature of such a structure is diagnostic of the absolute configuration of the amino acid by circular dichroism. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3987 / 3991
页数：5
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