Synthesis of Triangular Metallodendrimers via Coordination-Driven Self-Assembly

被引：33
作者：
Han, Qing [1 ]
Wang, Li-Lei [1 ]
Li, Quan-Jie [2 ]
Zhao, Guang-Zhen [1 ]
He, Jiuming [3 ,4 ]
Hu, Bingjie [5 ]
Tan, Hongwei [2 ]
Abliz, Zeper [3 ,4 ]
Yu, Yihua [5 ]
Yang, Hai-Bo [1 ]
机构：
[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
[2] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[3] Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
[4] Peking Union Med Coll, Beijing 100050, Peoples R China
[5] E China Normal Univ, Dept Phys, Shanghai Key Lab Magnet Resonance, Shanghai 200062, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 07期
关键词：
LIGHT-EMITTING-DIODES; SUPRAMOLECULAR CHEMISTRY; MOLECULAR ARCHITECTURE; METAL-COMPLEXES; SITE-ISOLATION; DENDRIMERS; HEXAGONS; ENCAPSULATION; CONSTRUCTION; POLYMERS;
D O I：
10.1021/jo300016a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new family of 60 degrees dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel "threecomponent" triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR (H-1 and P-31), H-1 DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.
引用
收藏
页码：3426 / 3432
页数：7
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