Halogen bonding organocatalysis enhanced through intramolecular hydrogen bonds

被引：25

作者：

Riel, Asia Marie S. ^{[1
]}

Decato, Daniel A. ^{[1
]}

Sun, Jiyu ^{[1
]}

Berryman, Orion B. ^{[1
]}

机构：

[1] Univ Montana, 32 Campus Dr, Missoula, MT 59812 USA

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 09期

基金：

美国国家科学基金会;

关键词：

ORGANIC FLUORINE; COOPERATIVITY; PREORGANIZATION; CATALYSIS;

D O I：

10.1039/d1cc05475a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent results indicate a halogen bond donor is strengthened through direct interaction with a hydrogen bond to the electron-rich belt of the halogen. Here, this Hydrogen Bond enhanced Halogen Bond (HBeXB) plays a clear role in a catalyst. Our HBeXB catalyst improves product conversion in a halide abstraction reaction over a traditional halogen bonding derivative.

引用

页码：1378 / 1381

页数：4

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