Hydrogen transfer reduction of ketones using formic acid as a hydrogen donor under hydrothermal conditions

被引：6

作者：

Shen, Zheng ^{[1
]}

Jin, Fang-ming ^{[1
]}

Zhang, Ya-lei ^{[1
]}

Wu, Bing ^{[1
]}

Cao, Jiang-lin ^{[1
]}

机构：

[1] Tongji Univ, Coll Environm Sci & Engn, MOE Key Lab Yangtze River Water Environm, State Key Lab Pollut Control & Resources Reuse, Shanghai 200092, Peoples R China

来源：

JOURNAL OF ZHEJIANG UNIVERSITY-SCIENCE A | 2009年 / 10卷 / 11期

关键词：

Hydrogen transfer reduction; Formic acid; Ketone; Hydrothermal reaction; MEERWEIN-PONNDORF-VERLEY; ASYMMETRIC TRANSFER HYDROGENATION; NICKEL NANOPARTICLES; SUPERCRITICAL WATER; CONVERSION; BIOMASS;

D O I：

10.1631/jzus.A0920097

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The hydrothermal experiments with ketones and formic acid showed that the hydrogen transfer reduction of ketones can be conducted using formic acid as a hydride donor in the presence of NaOH at 300 A degrees C. The yield of alcohols was considerably higher at a much lower ratio of hydrogen source to ketones than the traditional Meerwein-Ponndorf-Verley (MPV) reduction, reaching 60% for isopropanol from acetone and 70% for lactic acid from pyruvic acid. Water molecules may act as a catalyst in the hydrogen transfer reduction of ketones under hydrothermal conditions.

引用

页码：1631 / 1635

页数：5

共 23 条

[11] Kinetics of oxidation of food wastes with H2O2 in supercritical water
Jin, FM
Kishita, A
Moriya, T
Enomoto, H
[J]. JOURNAL OF SUPERCRITICAL FLUIDS, 2001, 19 (03) : 251 - 262
[12] CLASSICAL ORGANIC-REACTIONS IN PURE SUPERHEATED WATER
KUHLMANN, B
ARNETT, EM
SISKIN, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (11) : 3098 - 3101
[13] LAROCK RC, 1989, COMPREHENSIVE ORGANI, P35
[14] FORMATION OF ACICULAR MONOCLINIC ZIRCONIA PARTICLES UNDER HYDROTHERMAL CONDITIONS
LI, C
YAMAI, I
MURASE, Y
KATO, E
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (08) : 1479 - 1482
[15] An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine
Matharu, Daljit S.
Morris, David J.
Clarkson, Guy J.
Wills, Martin
[J]. CHEMICAL COMMUNICATIONS, 2006, (30) : 3232 - 3234
[16] Meerwein H, 1925, LIEBIGS ANN CHEM, V444, P221
[17] Regiospecific solvent-free transfer hydrogenation of α,β-unsaturated carbonyl compounds catalyzed by a cationic ruthenium(II) compound
Naskar, Sipra
Bhattacharjee, Manish
[J]. TETRAHEDRON LETTERS, 2007, 48 (03) : 465 - 467
[18] PONNDORF W, 1926, Z ANGEW CHEM, V39, P138, DOI DOI 10.1002/ANGE.19260390504
[19] Meerwein-Ponndorf-Verley reaction of acetophenones with 2-propanol over MgAl mixed oxide:: The substituent effect
Ruiz, Jose R.
Jimenez-Sanchidrian, Cesar
Hidalgo, Julia M.
[J]. CATALYSIS COMMUNICATIONS, 2007, 8 (07) : 1036 - 1040
[20] SHAW RW, 1991, CHEM ENG NEWS, V69, P26

← 1 2 3 →