Patterns of Diacetylene-Containing Peptide Amphiphiles Using Polarization Holography

被引:25
作者
van den Heuvel, Maaike [1 ]
Prenen, An M. [2 ]
Gielen, Jeroen C. [3 ]
Christianen, Peter C. M. [3 ]
Broer, Dick J. [2 ]
Lowik, Dennis W. P. M. [1 ]
van Hest, Jan C. M. [1 ]
机构
[1] Radboud Univ Nijmegen, Dept Bioorgan Chem, NL-6525 ED Nijmegen, Netherlands
[2] Eindhoven Univ Technol, Dept Polymer Chem & Technol, NL-5600 MB Eindhoven, Netherlands
[3] Radboud Univ Nijmegen, HFML, NL-6525 ED Nijmegen, Netherlands
关键词
POLYDIACETYLENE SUPRAMOLECULES; POLYMERIZATION;
D O I
10.1021/ja9054756
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The polarization dependence of a diacetylene polymerization was studied. For this purpose, peptide amphiphile fibers with a diacetylene moiety, which could only polymerize in the direction of the fiber, were employed. If nonaligned samples were illuminated with polarized light, only the fibers parallel to the polarization direction of the light were polymerized With magnetically aligned fibers, spatially selective polymerization was accomplished using polarization holography.
引用
收藏
页码:15014 / 15017
页数:4
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