Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source

被引：128

作者：

Cao, Jian ^{[1
]}

Zheng, Zhan-Jiang ^{[1
]}

Xu, Zheng ^{[1
]}

Xu, Li-Wen ^{[1
,2
]}

机构：

[1] Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China

[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2017年 / 336卷

关键词：

Carbonylation; Transition-metal catalysis; Non-gaseous C1 source; CO surrogates; KHAND-TYPE REACTIONS; FORMIC-ACID; CO GAS; CARBON-MONOXIDE; H ACTIVATION; TRANSFER HYDROFORMYLATION; OXIDATIVE CARBONYLATION; ASYMMETRIC-SYNTHESIS; HYDROGEN-PRODUCTION; ALIPHATIC-AMINES;

D O I：

10.1016/j.ccr.2017.01.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

While carbon monoxide (CO) gas has been extensively applied in the bulk chemical industry, its intrinsic properties such as high toxicity, flammability, and special equipment requirement for handling, limit its utilization in organic synthesis, fine chemical industry and academia. Recently, considerable effort has been devoted to the development of CO surrogates to avoid the direct use of carbon monoxide gas. Among the various CO surrogates, formic acid and formaldehyde, have a broad range of applications in organic synthesis. The direct carbonylation with formic acid (HCOOH) and formaldehyde (HCHO) represents one of the most atom-economical substitutes owing to their high weight percentage of CO. In this review, the potential roles of both formic acid and formaldehyde in transition-metal catalyzed carbonylation reactions are discussed. In order to understand these transfer carbonylation reactions, the mechanistic rationale for representative examples is also provided. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：43 / 53

页数：11

共 86 条

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