Near-Infrared Broadband ZnTa2O6:Cr3+ Phosphor for pc-LEDs and Its Application to Nondestructive Testing

被引:32
作者
He, Shaoxuan [1 ]
Li, Panlai [1 ]
Ren, Yinti [1 ]
Wei, Guohui [1 ]
Wang, Ye [1 ]
Yang, Yuanbo [1 ]
Li, Rui [1 ]
Li, Jiehong [1 ]
Shi, Yawei [1 ]
Shi, Xingqiang [1 ]
Wang, Zhijun [1 ]
机构
[1] Hebei Univ, Coll Phys Sci & Technol, Hebei Key Lab Opt Elect Informat & Mat, Baoding 071002, Peoples R China
基金
中国国家自然科学基金;
关键词
LIGHT-EMITTING-DIODES; HIGHLY EFFICIENT; SITE OCCUPANCY; EMISSION; LUMINESCENCE; MN4+;
D O I
10.1021/acs.inorgchem.2c01403
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Broadband near-infrared (NIR) phosphors are necessary materials for developing portable NIR light sources. Moreover, exploiting an NIR phosphor with a main peak located beyond a wavelength of 900 nm remains a challenge because this spectral range has great potential in biological nondestructive testing and solution testing. In this study, a range of Cr3+-doped ZnTa2O6 (ZTO) phosphors were completely synthesized by a solid-state method, which show broadband Cr3+ emission centered at 935 nm with a large full width at half maximum (FWHM) of 185 nm due to two distorted octahedral sites. A packaged phosphor-converted light-emitting diode (pc-LED) device is used to penetrate a 5-cm-thick chicken breast and identify diverse solutions based on differences in the measured transmission spectra. The results indicate broad application prospects in the field of biological tissue penetration and solution analysis.
引用
收藏
页码:11284 / 11292
页数:9
相关论文
共 45 条
[1]   Pushing the Limit of Boltzmann Distribution in Cr3+-Doped CaHfO3 for Cryogenic Thermometry [J].
Back, Michele ;
Ueda, Jumpei ;
Brik, Mikhail G. ;
Tanabe, Setsuhisa .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (34) :38325-38332
[2]   QUANTITATIVE-ANALYSIS IN DIFFUSE-REFLECTANCE SPECTROMETRY - A MODIFIED KUBELKA-MUNK EQUATION [J].
CHRISTY, AA ;
KVALHEIM, OM ;
VELAPOLDI, RA .
VIBRATIONAL SPECTROSCOPY, 1995, 9 (01) :19-27
[3]   Assessment of the Perdew-Burke-Ernzerhof exchange-correlation functional [J].
Ernzerhof, M ;
Scuseria, GE .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (11) :5029-5036
[4]   Ultra-high-efficiency near-infrared Ga2O3:Cr3+phosphor and controlling of phytochrome [J].
Fang, Mu-Huai ;
De Guzman, Gabriel Nicolo A. ;
Bao, Zhen ;
Majewska, Natalia ;
Mahlik, Sebastian ;
Grinberg, Marek ;
Leniec, Grzegorz ;
Kaczmarek, Slawomir M. ;
Yang, Chia-Wei ;
Lu, Kuang-Mao ;
Sheu, Hwo-Shuenn ;
Hu, Shu-Fen ;
Liu, Ru-Shi .
JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (32) :11013-11017
[5]   Penetrating Biological Tissue Using Light-Emitting Diodes with a Highly Efficient Near-Infrared ScBO3:Cr3+ Phosphor [J].
Fang, Mu-Huai ;
Huang, Po-Yuan ;
Bao, Zhen ;
Majewska, Natalia ;
Lesniewski, Tadeusz ;
Mahlik, Sebastian ;
Grinberg, Marek ;
Leniec, Grzegorz ;
Kaczmarek, Slawomir M. ;
Yang, Chia-Wei ;
Lu, Kuang-Mao ;
Sheu, Hwo-Shuenn ;
Liu, Ru-Shi .
CHEMISTRY OF MATERIALS, 2020, 32 (05) :2166-2171
[6]   A brief review on the history of human functional near-infrared spectroscopy (fNIRS) development and fields of application [J].
Ferrari, Marco ;
Quaresima, Valentina .
NEUROIMAGE, 2012, 63 (02) :921-935
[7]   A highly efficient and thermally stable broadband Cr3+-activated double borate phosphor for near-infrared light-emitting diodes [J].
Huang, Decai ;
Zhu, Haomiao ;
Deng, Zhonghua ;
Yang, Hongyi ;
Hu, Jie ;
Liang, Sisi ;
Chen, Dejian ;
Ma, En ;
Guo, Wang .
JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (01) :164-172
[8]   Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources [J].
Jia, Zhenwei ;
Yuan, Chenxu ;
Liu, Yongfu ;
Wang, Xiao-Jun ;
Sun, Peng ;
Wang, Lei ;
Jiang, Haochuan ;
Jiang, Jun .
LIGHT-SCIENCE & APPLICATIONS, 2020, 9 (01)
[9]   Broadband infrared LEDs based on europium-to-terbium charge transfer luminescence [J].
Joos, Jonas J. ;
Van der Heggen, David ;
Martin, Lisa I. D. J. ;
Amidani, Lucia ;
Smet, Philippe F. ;
Barandiaran, Zoila ;
Seijo, Luis .
NATURE COMMUNICATIONS, 2020, 11 (01)
[10]   Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set [J].
Kresse, G ;
Furthmuller, J .
PHYSICAL REVIEW B, 1996, 54 (16) :11169-11186