Self-assembling of supramolecular adducts by sulfonato-calix[4]arene and pyridinium gemini guests in neutral aqueous solution

被引：12

作者：

Bonaccorso, Carmela ^{[1
]}

Migliore, Rossella ^{[1
]}

Volkova, Mariia A. ^{[2
]}

Arena, Giuseppe ^{[1
]}

Sgarlata, Carmelo ^{[1
]}

机构：

[1] Univ Catania, Dipartimento Sci Chim, Viale Andrea Doria 6, I-95125 Catania, Italy

[2] Ivanovo State Univ Chem & Technol, Dept Gen Chem Technol, Sheremetev Av 7, Ivanovo 153000, Russia

来源：

THERMOCHIMICA ACTA | 2017年 / 656卷

关键词：

Host-guest complex; Water-soluble calixarene; Gemini guest; Capsular-like adduct; Driving forces; Isothermal titration calorimetry; P-SULFONATOCALIXARENES; WATER; HOST; THERMODYNAMICS; INCLUSION; MOLECULES; ENTHALPY; CATIONS; ALKANES; ANIONS;

D O I：

10.1016/j.tca.2017.08.009

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The formation of self-assembled structures triggered by pyridinium-based gemini guests in the presence of a sulfonato-calix[4]arene receptor has been thoroughly examined via isothermal titration calorimetry (ITC) in neutral aqueous solution. Data confirm the existence of a 1:1 host guest complex, in which the guest is strongly bound to the host cavity, and the formation of a 2:1 capsular-like adduct. The splitting of the Delta G degrees term into the enthalpic and entropic contributions allowed to highlight the often opposing forces driving the encapsulation process which strongly depend on the size and shape of the gemini guest.

引用

页码：47 / 52

页数：6

共 18 条

[11] Self-assembling of p-tert-butylcalix[4]arene into supramolecular structures using transition-metal derivatization
ZanottiGerosa, A
Solari, E
Giannini, L
Floriani, C
ChiesiVilla, A
Rizzoli, C
CHEMICAL COMMUNICATIONS, 1996, (02) : 119 - 120
[12] Thermodynamics of self-assembling of mixture of a cationic gemini surfactant and sodium dodecylsulfate in aqueous solution: Calorimetry, conductivity and surface pressure measurements
Bai, Guangyue
Wang, Yujie
Ding, Yanhong
Zhuo, Kelei
Wang, Jianji
Bastos, Margarida
JOURNAL OF CHEMICAL THERMODYNAMICS, 2016, 94 : 221 - 229
[13] Sequence, Stoichiometry, and Dimensionality Control in Porphyrin/Bis-calix[4]arene Self-Assemblies in Aqueous Solution
D'Urso, Alessandro
Cristaldi, Domenico Andrea
Fragala, Maria Elena
Gattuso, Giuseppe
Pappalardo, Andrea
Villari, Valentina
Micali, Norberto
Pappalardo, Sebastiano
Parisi, Melchiorre F.
Purrello, Roberto
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (34) : 10439 - 10446
[14] Molecular Recognition of Hydrocarbon Guests by a Supramolecular Capsule Formed by the 4:4 Self-Assembly of Tris(Zn2+-Cyclen) and Trithiocyanurate in Aqueous Solution
Aoki, Shin
Suzuki, Satoshi
Kitamura, Masanori
Haino, Takeharu
Shiro, Motoo
Zulkefeli, Mohd
Kimura, Eiichi
CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (05) : 944 - 956
[15] Self-assembling, patterning and SPR imaging of a 1,3 alternate bis(dipyridyl)calix[4] arene derivative -: Cu2+ complex immobilized on to Au(111) surfaces
Arena, G
Contino, A
Longo, E
Sgarlata, C
Spoto, G
Zito, V
CHEMICAL COMMUNICATIONS, 2004, (16) : 1812 - 1813
[16] SYNTHESIS OF A NOVEL AMPHIPHILE, 4-[4-(4-DECYLOXYPHENYLAZO) NAPHTHYLOXY] BUTYL TRIMETHYLAMMONIUM BROMIDE, AND ITS SELF-ASSEMBLING BEHAVIOR IN DILUTE AQUEOUS SOLUTION
Guo Wen LI
ChineseChemicalLetters, 1991, (10) : 817 - 820
[17] A cuboctahedral supramolecular capsule by 4:4 self-assembly of tris(ZnII-cyclen) and trianionic trithiocyanurate in aqueous solution at neutral pH (cyclen=1,4,7,10-tetraazacyclododecane)
Aoki, S
Shiro, M
Kimura, E
CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (04) : 929 - 939
[18] Supramolecular Self-Assembling of [HgII(RC6H4NNNC6H4R)2Py] [R = EtOC(O)] through Reciprocal Metal-η2-arene π-Interactions and Non Classical C-H•••O Bonding: Synthesis and X-ray Characterization of a Bis Diaryl Symmetric-substituted Triazenide Complex Polymer of Hg(II)
Hoerner, Manfredo
de Oliveira, Gelson M.
Villis, Paulo C. M.
Visentin, Lorenzo do C.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2008, 19 (08) : 1641 - 1645

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