DISPERSION OF PRISTINE MULTI-WALLED CARBON NANOTUBES IN COMMON ORGANIC SOLVENTS

被引:33
作者
Sun, Guoxing [1 ,2 ]
Liu, Zhengping [1 ]
Chen, Guangming [2 ]
机构
[1] Beijing Normal Univ, Inst Polymer Chem & Phys, Coll Chem, BNU Key Lab Environmentally Friendly & Funct Poly, Beijing 100875, Peoples R China
[2] Chinese Acad Sci, Inst Chem, New Mat Lab, BNLMS, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
Dispersion; multi-walled carbon nanotubes; organic solvents; pristine; AMIDE SOLVENTS; WATER; SOLUBILIZATION; DISSOLUTION; FRACTION; FILMS;
D O I
10.1142/S1793292010001986
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The dispersion of pristine multi-walled carbon nanotubes in various common organic solvents and water has been investigated. Sedimentation tests, optical microscopy, transmission electron microscopy and Tyndall effect tests are employed. The results clearly show that N-methyl-2-pyrrolodone, acetone, tetrahydrofuran and dichloromethane are good solvents to debundle and disperse the multi-walled carbon nanotubes. In contrast, much precipitation can be obviously observed for systems of the carbon nanotubes in water, ethanol and toluene. Additionally, Tyndall effect tests suggest that the upper dispersions of the carbon nanotubes in acetone, tetrahydrofuran and dichloromethane with a concentration of 0.1 mg/mL and the dispersion of carbon nanotubes in N-methyl-2-pyrrolodone with a concentration of 0.05 mg/mL are colloidal systems rather than solutions. Finally, based on the above results, a possible mechanism is briefly discussed.
引用
收藏
页码:103 / 109
页数:7
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