DISPERSION OF PRISTINE MULTI-WALLED CARBON NANOTUBES IN COMMON ORGANIC SOLVENTS

被引:33
|
作者
Sun, Guoxing [1 ,2 ]
Liu, Zhengping [1 ]
Chen, Guangming [2 ]
机构
[1] Beijing Normal Univ, Inst Polymer Chem & Phys, Coll Chem, BNU Key Lab Environmentally Friendly & Funct Poly, Beijing 100875, Peoples R China
[2] Chinese Acad Sci, Inst Chem, New Mat Lab, BNLMS, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
Dispersion; multi-walled carbon nanotubes; organic solvents; pristine; AMIDE SOLVENTS; WATER; SOLUBILIZATION; DISSOLUTION; FRACTION; FILMS;
D O I
10.1142/S1793292010001986
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The dispersion of pristine multi-walled carbon nanotubes in various common organic solvents and water has been investigated. Sedimentation tests, optical microscopy, transmission electron microscopy and Tyndall effect tests are employed. The results clearly show that N-methyl-2-pyrrolodone, acetone, tetrahydrofuran and dichloromethane are good solvents to debundle and disperse the multi-walled carbon nanotubes. In contrast, much precipitation can be obviously observed for systems of the carbon nanotubes in water, ethanol and toluene. Additionally, Tyndall effect tests suggest that the upper dispersions of the carbon nanotubes in acetone, tetrahydrofuran and dichloromethane with a concentration of 0.1 mg/mL and the dispersion of carbon nanotubes in N-methyl-2-pyrrolodone with a concentration of 0.05 mg/mL are colloidal systems rather than solutions. Finally, based on the above results, a possible mechanism is briefly discussed.
引用
收藏
页码:103 / 109
页数:7
相关论文
共 50 条
  • [1] Improving dispersion of multi-walled carbon nanotubes and graphene using a common non-covalent modifier
    Kwon, Youbin
    Shim, Wonbo
    Jeon, Seung-Yeol
    Youk, Ji-Ho
    Yu, Woong-Ryeol
    CARBON LETTERS, 2016, 20 (01) : 53 - 61
  • [2] Microwave Irradiation of Pristine Multi-Walled Carbon Nanotubes in Vacuum
    Alvarez-Zauco, Edgar
    Basiuk, Vladimir A.
    Acosta-Najarro, Dwight
    Flores-Morales, Carlos
    Puente-Lee, Ivan
    Bassiouk, Maria
    Gromovoy, Taras Yu.
    Mischanchuk, Boris G.
    Basiuk, Elena V.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2010, 10 (01) : 448 - 455
  • [3] Hydrogen Passivation Induced Dispersion of Multi-Walled Carbon Nanotubes
    Yang, Yingchao
    Xu, Zhi-Hui
    Pan, Zhengwei
    Li, Xiaodong
    ADVANCED MATERIALS, 2012, 24 (07) : 881 - +
  • [4] Wet-grinding assisted ultrasonic dispersion of pristine multi-walled carbon nanotubes (MWCNTs) in chitosan solution
    Tang, Changyu
    Zhou, Tiannan
    Yang, Jinghui
    Zhang, Qin
    Chen, Feng
    Fu, Qiang
    Yang, Li
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2011, 86 (01) : 189 - 197
  • [5] Surface modification and dispersion of multi-walled carbon nanotubes
    Lu Zhihua
    Sun Kangning
    Ren Shuai
    Jiao Mingchun
    RARE METAL MATERIALS AND ENGINEERING, 2007, 36 : 100 - 103
  • [6] Dispersion Characteristics of Multi-Walled Carbon Nanotubes with Gallic Acid
    Jiang, Xiaosong
    Shao, Zhenyi
    Li, Jingrui
    Liu, Wanxia
    Zhu, Degui
    Liu, Dan
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2015, 15 (12) : 9874 - 9878
  • [7] Dispersion and Shortening of Multi-Walled Carbon Nanotubes by Size Modification
    Jang, Byung-Koog
    Sakka, Yoshio
    MATERIALS TRANSACTIONS, 2010, 51 (01) : 192 - 195
  • [8] Influence of Polyvinyl Pyrrolidone on the Dispersion of Multi-Walled Carbon Nanotubes in Aqueous Solution
    Wang, Baomin
    Liu, Shuai
    Zhu, Yu
    Ge, Shukui
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (13) : 2385 - 2390
  • [9] Tailoring Triblock Copolymers for Dispersion of Individual, Pristine, Single-Walled Carbon Nanotubes in Organic Solvents
    Itzhak, Racheli
    Raichman, Daniel
    Shahar, Zahi
    Frey, Gitti L.
    Frey, Joseph
    Yerushalmi-Rozen, Rachel
    JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (09): : 3748 - 3753
  • [10] Modification and dispersion of multi-walled carbon nanotubes in water
    He, Z. H.
    Gao, G. B.
    Zhang, Y. M.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (07) : 1191 - 1195