Rhodium-mediated formation of peroxides from dioxygen: Isolation of hydroperoxo, silylperoxo, and methylperoxo intermediates

被引：64
作者：
Ahijado, M
Braun, T
Noveski, D
Kocher, N
Neumann, B
Stalke, D
Stammler, HG
机构：
[1] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany
[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 42期
关键词：
fluorinated ligands; oxygenation; peroxides; peroxo complexes; rhodium;
D O I：
10.1002/anie.200501615
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Out of thin air, a rhodium complex converts molecular oxygen into hydrogen peroxide, bis(trimethylsilyl) peroxide, and methyl hydroperoxide. Intermediate η1-hydroperoxo and η1-silylperoxo, and η1-methylperoxo complexes have been isolated. Another η1-methylperoxo (see picture) and an η1- hydroperoxo complex have been characterized by X-ray crystallography. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：6947 / 6951
页数：5
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