Activation of persulfate by green nano-zero-valent iron-loaded biochar for the removal of p-nitrophenol: Performance, mechanism and variables effects

In this study, with the green tea extraction solution as a reducing agent and green tea residues as a raw material of biochar, green nano zero-valent iron biochar (G-nZVI-BC) was prepared with the green synthesis method and then combined with potassium persulfate to degrade p-nitrophenol in water. Compared with zero-valent ironloaded biochar (C-nZVI-BC) prepared by the traditional chemical liquid phase synthesis method, G-nZVI-BC containing tea polyphenols further improved dispersibility of Fe0 on biochar, prevented nZVI agglomeration on BC, and promoted PNP degradation. The system constructed by G-nZVI-BC/PDS showed the high oxidation resistance than the C-nZVI-BC/PDS system, thus endowing the synthesis material with long-term reactivity. Both the radical pathway and non-radical pathways contributed to catalytic degradation and free radicals played a key role. The G-nZVI-BC/PDS system realized the good removal effect on PNP in the pH range of 3.06-9.23. The reusability of G-nZVI-BC and the PNP removal effect in water body conditions indicated that G-nZVI-BC had a good application prospect in the field of water treatment.