1,5,9-Triazacoronenes: A Family of Polycyclic Heteroarenes Synthesized by a Threefold Pictet-Spengler Reaction

被引:95
作者
Wei, Junfa [1 ]
Han, Bo [1 ]
Guo, Qiang [1 ]
Shi, Xianying [1 ]
Wang, Wenliang [1 ]
Wei, Ni [1 ]
机构
[1] Shaanxi Normal Univ, Key Lab Macromol Sci Shaanxi Prov, Sch Chem & Mat Sci, Xian 710062, Peoples R China
关键词
electrochemistry; heterocycles; optoelectronics; polycycles; triazacoronenes; FIELD-EFFECT TRANSISTORS; ELECTROGENERATED CHEMILUMINESCENCE; LIQUID-CRYSTALLINE; SMALL MOLECULES; CORONENE; ELECTRONICS; DENDRIMERS; SYSTEM;
D O I
10.1002/anie.201002369
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We are family: Triazacoronene derivatives have been synthesized in four steps from veratrole by using a threefold Pictet-Spengler reaction as the key step (see picture). They have good photophysical and electronical properties, thermal stability, and solubility, thus rendering them promising candidates as electron-transport materials. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:8209 / 8213
页数:5
相关论文
共 66 条
[1]   Liquid-crystalline and electron-deficient coronene oligocarboxylic esters and imides by twofold benzogenic Diels-Alder reactions on perylenes [J].
Alibert-Fouet, Sonia ;
Seguy, Isabelle ;
Bobo, Jean-Francois ;
Destruel, Pierre ;
Bock, Harald .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (06) :1746-1753
[2]  
Allard S., 2008, Angew. Chem, V120, P4138
[3]   Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].
Allard, Sybille ;
Forster, Michael ;
Souharce, Benjamin ;
Thiem, Heiko ;
Scherf, Ullrich .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098
[4]  
[Anonymous], ANGEW CHEM INT ED
[5]  
[Anonymous], ANGEW CHEM
[6]  
[Anonymous], 2007, ANGEW CHE
[7]  
Anthony J. E., 2008, ANGEW CHEM, V120, P460
[8]   The larger acenes: Versatile organic semiconductors [J].
Anthony, John E. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :452-483
[9]   Materials and Applications for Large Area Electronics: Solution-Based Approaches [J].
Arias, Ana Claudia ;
MacKenzie, J. Devin ;
McCulloch, Iain ;
Rivnay, Jonathan ;
Salleo, Alberto .
CHEMICAL REVIEWS, 2010, 110 (01) :3-24
[10]   Very high-efficiency green organic light-emitting devices based on electrophosphorescence [J].
Baldo, MA ;
Lamansky, S ;
Burrows, PE ;
Thompson, ME ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 1999, 75 (01) :4-6