An aqueous silica gel disperse electrolysis system.: N-Oxyl-mediated electrooxidation of alcohols

被引：68

作者：

Tanaka, H ^{[1
]}

Kawakami, Y ^{[1
]}

Goto, K ^{[1
]}

Kuroboshi, M ^{[1
]}

机构：

[1] Okayama Univ, Fac Engn, Dept Appl Chem, Okayama 7008530, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 03期

关键词：

electrochemistry; oxidation; alcohols; enantioselective;

D O I：

10.1016/S0040-4039(00)01979-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Oxyl-mediated electrooxidation of alcohols was performed in an aqueous silica gel disperse system. The newly devised electrolysis system offers an organic solvent-free and operationally simple procedure for oxidation of alcohols and could be successfully applied to kinetic resolution of sec-alcohol as well as enantioselective oxidation of meso-1,4-diol affording optically active gamma -lactone. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：445 / 448

页数：4

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