Synthesis and structural characterization of a novel tin(II) phosphonate, Sn2(O3PCH3)(C2O4)

被引：54

作者：

Adair, B ^{[1
]}

Natarajan, S ^{[1
]}

Cheetham, AK ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1998年 / 8卷 / 06期

关键词：

D O I：

10.1039/a800488i

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The title compound, Sn-2(O3PCH3)(C2O4), was synthesized hydrothermally using methylphosphonic acid and tin oxalate in the presence of butylamine. It crystallizes in the monoclinic space group P2(1)/m (no. 14) with the lattice-parameters a=4.723(1), b=15.196(1), c=6.147(1) Angstrom, beta=102.1(1)degrees, V=431.3(1) Angstrom(3), Z=4. The final R values are R=2.99, R-w=6.1 and S=1.04. The structure comprises a network of vertex-linked truncated square-pyramidal SnO4 units and tetrahedral O3PC units which gives rise to three-membered rings, via a three-coordinate oxygen, which are linked together forming one-dimensional chains. These chains are connected together via the oxalate group forming the structure.

引用

页码：1477 / 1479

页数：3

共 23 条

[1] Synthesis and structure of Cs[(VO)(2)(OH)(O3PCH2CH2PO3)]: A two-dimensional solid with pillared layers [J].

Bonavia, GH ;

Haushalter, RC ;

Lu, SH ;

OConner, CJ ;

Zubieta, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 132 (01) :144-150

[2] AlMePO-beta: inclusion and thermal removal of structure directing agent and the topotactic reconstructive transformation to its polymorph AlMePO-alpha [J].

Carter, VJ ;

Wright, PA ;

Gale, JD ;

Morris, RE ;

Sastre, E ;

PerezPariente, J .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (11) :2287-2292

[3]

CHEN JS, 1994, ANGEW CHEM INT EDIT, V33, P639, DOI 10.1002/anie.199406391

[4] SYNTHESIS OF OPEN-FRAMEWORK TRANSITION-METAL PHOSPHATES USING ORGANOMETALLIC PRECURSORS IN ACIDIC MEDIA - PREPARATION AND STRUCTURAL CHARACTERIZATION OF FE5P4O20H10 AND NAFE3P3O121 [J].

CORBIN, DR ;

WHITNEY, JF ;

FULTZ, WC ;

STUCKY, GD ;

EDDY, MM ;

CHEETHAM, AK .

INORGANIC CHEMISTRY, 1986, 25 (14) :2279-2280

[5]

Cotton F.A., 1988, Advanced Inorganic Chemistry

[6] Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate [J].

Feng, PY ;

Bu, XH ;

Stucky, GD .

NATURE, 1997, 388 (6644) :735-741

[7] Two new tetramethylammonium zinc phosphates: N(CH3)(4)center dot Zn(HPO4)(H2PO4), an open framework phase built up from a low-density 12-ring topology, and N(CH3)(4)center dot Zn(H2PO4)(3), a molecular cluster [J].

Harrison, WTA ;

Hannooman, L .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 131 (02) :363-369

[8] N(CH3)(4).ZnH3(PO4)(2): A large-pore zincophosphate built up from a 12-ring architecture with a remarkably low tetrahedral-framework-atom density [J].

Harrison, WTA ;

Hannooman, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06) :640-641

[9] STRUCTURE OF A 3-DIMENSIONAL, MICROPOROUS MOLYBDENUM PHOSPHATE WITH LARGE CAVITIES [J].

HAUSHALTER, RC ;

STROHMAIER, KG ;

LAI, FW .

SCIENCE, 1989, 246 (4935) :1289-1291

[10] CRYSTAL-STRUCTURE OF STANNOUS HYDROXIDE PHOSPHATE, A REACTION-PRODUCT OF STANNOUS FLUORIDE AND APATITE [J].

JORDAN, TH ;

SCHROEDER, LW ;

DICKENS, B ;

BROWN, WE .

INORGANIC CHEMISTRY, 1976, 15 (08) :1810-1814

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