Hexanitrato complexes and hybrid double perovskites of Am3+ and Cm3+

被引：4

作者：

Tarlton, Michael L. ^{[1
]}

Skanthakumar, Suntharalingam ^{[1
]}

Vallet, Valerie ^{[2
]}

Wilson, Richard E. ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, 9700 SCass Ave, Lemont, IL 60439 USA

[2] Univ Lille, UMR 8523 PhLAM Phys Lasers Atomes & Mol, CNRS, F-59000 Lille, France

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 85期

关键词：

STRUCTURAL PERIODICITY; CRYSTAL-STRUCTURES; NITRATE COMPLEXES; BERKELIUM; ACTINIDE; SPECTROSCOPY; CHEMISTRY; COVALENCY; CATIONS;

D O I：

10.1039/d2cc05162a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structures of the homoleptic hexanitrato complexes of Am(iii) and Cm(iii), [(CH3)(4)N](2)KAn(NO3)(6) are reported. These compounds form a double perovskite structure type, A(2)B ' BX6, crystallizing in the cubic space group Fm3m. Their electronic properties, as calculated using the Quantum Theory of Atoms in Molecules, are reported and compared to their lanthanide homologues Eu(iii) and Gd(iii).

引用

页码：11997 / 12000

页数：4

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