Ring-driven shear thickening in wormlike micelles?

被引:32
作者
Cates, ME
Candau, SJ
机构
[1] Univ Edinburgh, Dept Phys & Astron, Edinburgh EH9 3JZ, Midlothian, Scotland
[2] Univ Strasbourg, Lab Dynam Fluides Complexes, UMR7506, F-67070 Strasbourg, France
来源
EUROPHYSICS LETTERS | 2001年 / 55卷 / 06期
关键词
D O I
10.1209/epl/i2001-00359-2
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The shear-thickening behaviour of wormlike micelles, at concentrations just below overlap, remains unexplained. In some cases, it has recently been confirmed that very slow relaxations must be present even in the quiescent state for example, the shear-thickening properties can depend on earlier thermal cycling. We present a speculative scenario based on the presence, just below the ( apparent) overlap threshold, of large rings whose linking and delinking kinetics control the shear-thickening process. Equilibration between rings and open chains in turn controls the slow relaxations.
引用
收藏
页码:887 / 893
页数:7
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