Simple and expeditious pinacol coupling of non usual α,β-unsaturated carbonyl compounds in water

被引：7

作者：

Billamboz, Muriel ^{[1
]}

Sotto, Nicolas ^{[1
]}

Chevrin-Villette, Carole ^{[1
]}

Len, Christophe ^{[1
,2
]}

机构：

[1] Univ Technol Compiegne, Univ Paris 04, Ecole Super Chim Organ & Minerale, Ctr Rech Royallieu,EA Transformat Integrees Matie, F-60205 Compiegne, France

[2] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

来源：

RSC ADVANCES | 2015年 / 5卷 / 57期

关键词：

AQUEOUS-MEDIA; AROMATIC-ALDEHYDES; ORGANIC-SYNTHESIS; ULTRASOUND IRRADIATION; CATALYTIC-SYSTEM; ARYL ALDEHYDES; REDUCTION; KETONES; MAGNESIUM; ALUMINUM;

D O I：

10.1039/c5ra03870g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using zinc (0) in a 5% v AcOH aqueous solution allowed the efficient pinacol coupling of aliphatic or aromatic unusual, alpha, beta-unsaturated carbonyl compounds such as citral A in good to excellent yields (56-99%). It can also be successfully applied to acetophenone.

引用

页码：46026 / 46030

页数：5

共 18 条

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