Chlorine ion sensor based on polyaniline film electrode

被引:13
作者
Li, XX [1 ]
Ju, M [1 ]
Li, XW [1 ]
机构
[1] Nanjing Univ Sci & Technol, Dept Chem, Nanjing 210094, Peoples R China
关键词
polyaniline; chemical sensor; chlorine ion; electrochemistry;
D O I
10.1016/j.snb.2003.08.006
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Polyaniline film electrode was prepared by electrochemical method, and was characterized by Fourier-transform infrared (FTIR) spectra, wide-angle X-ray diffraction (WAXD) and transmission electron microscope (TEM). The sensing property of polyaniline film electrode for chlorine ion was studied by flow injection analysis. These results show that polyaniline film electrode possesses high the sensitivity and fast response time for chlorine ion, and the relationship between logarithm of maximum response current and the chlorine ion concentration is linear: lg I-max = 0.8760 lg C + 45.32, in the range of 10(-5) to 10(-2) Mol/l concentrations. Lifetime of polyaniline film electrode is about 35,000 measurement numbers. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:146 / 149
页数:4
相关论文
共 9 条
[1]   An optical gas sensor based on polyaniline Langmuir-Blodgett films [J].
Agbor, NE ;
Cresswell, JP ;
Petty, MC ;
Monkman, AP .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 41 (1-3) :137-141
[2]   POLYANILINE THIN-FILMS FOR GAS-SENSING [J].
AGBOR, NE ;
PETTY, MC ;
MONKMAN, AP .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 28 (03) :173-179
[3]   Acrylic acid doped polyaniline as an ammonia sensor [J].
Chabukswar, VV ;
Pethkar, S ;
Athawale, AA .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 77 (03) :657-663
[4]   Application of conducting polyaniline as sensor material for ammonia [J].
Dhawan, SK ;
Kumar, D ;
Ram, MK ;
Chandra, S ;
Trivedi, DC .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 40 (2-3) :99-103
[5]   Conducting polymers prepared by oxidative polymerization: Polyaniline [J].
Gospodinova, N ;
Terlemezyan, L .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (08) :1443-1484
[6]   Polyaniline: A polymer with many interesting intrinsic redox states [J].
Kang, ET ;
Neoh, KG ;
Tan, KL .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (02) :277-324
[7]   Polyaniline and polypyrrole: Where are we headed? [J].
MacDiarmid, AG .
SYNTHETIC METALS, 1997, 84 (1-3) :27-34
[8]   Chloroform vapour sensor based on copper/polyaniline nanocomposite [J].
Sharma, S ;
Nirkhe, C ;
Pethkar, S ;
Athawale, AA .
SENSORS AND ACTUATORS B-CHEMICAL, 2002, 85 (1-2) :131-136
[9]   Fabrication and characterization of polyaniline-based gas sensor by ultra-thin film technology [J].
Xie, D ;
Jiang, YD ;
Pan, W ;
Li, D ;
Wu, ZM ;
Li, YR .
SENSORS AND ACTUATORS B-CHEMICAL, 2002, 81 (2-3) :158-164