Syntheses and characterization of two palladium (II) complexes with p-ClC6H4-HIEAI ligand and crystal structure of PdCl(p-ClC6H4-IEAI)(p-ClC6H4NH2)

被引：0

作者：

Feng, YL

Liu, SX ^{[1
]}

机构：

[1] Fuzhou Univ, Cent Lab, Fuzhou 350002, Peoples R China

[2] Zhejiang Normal Univ, Inst Phys Chem, Jinhua 321004, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 19卷 / 10期

关键词：

palladium complex; isonitrosoethylacetoacetate; Schiff base; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two palladium 0 complexes with the ligand p-ClC6H4-HIEAI [p-ClC6H4-HIEAI = isonitrosoethylacetoacetate-N-(p-chlorobenzyl)imine], PdCl(p-ClC6H4-IEAI) (p-ClC6H4NH2) (1) and Pd(p-ClC6H4-IEAI)(2) (2), were prepared and characterized by IR and electronic spectroscopy. The crystal structure of I has been determined. The geometry around the palladium atom in 1 is a distorted square plane, the Schiff base ligand p-ClC6H4-IEAI(-) being coordinated to Pd atom through its oximo-nitrogen atoms and imino-nitrogen atoms. CCDC: 180873.

引用

页码：1141 / 1144

页数：4

共 18 条

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