Silica Nanoparticles as a Highly Efficient Catalyst for the One-Pot Synthesis of 2-Hydroxyacetamide Derivatives from Isocyanides and Electron-Poor Aromatic Aldehydes

被引：24

作者：

Ramazani, Ali ^{[1
]}

Mahyari, Amir ^{[1
]}

Lashgari, Hamed ^{[2
]}

Slepokura, Katarzyna ^{[3
]}

Lis, Tadeusz ^{[3
]}

机构：

[1] Zanjan Univ, Dept Chem, Zanjan, Iran

[2] Payame Noor Univ, Dept Chem, Abhar, Zanjan, Iran

[3] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

HELVETICA CHIMICA ACTA | 2011年 / 94卷 / 04期

关键词：

SOLVENT-FREE CONDITIONS; STABILIZED PHOSPHORUS YLIDES; BENZOIC-ACID DERIVATIVES; ONE-STEP SYNTHESIS; ACETYLENIC ESTERS; STEREOSELECTIVE-SYNTHESIS; 3-COMPONENT REACTION; GEL POWDER; CONVERSION; (N-ISOCYANIMINO)TRIPHENYLPHOSPHORANE;

D O I：

10.1002/hlca.201000280

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of an isocyanide with an electron-poor aromatic aldehyde in the presence of silica nanoparticles (silica NP; ca. 42 nm) proceeds smoothly at room temperature to afford 2-hydroxyacetamide derivatives in high yields (Scheme 1 and Table 1).

引用

页码：611 / 622

页数：12

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